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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
67562-19-0
合成路线
（共 11 条）
1360649-09-7
→
反应条件
67562-19-0
+
1360649-35-9
反应条件
(η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen in dichloromethane T=50°C; P=3750.38 Torr; 18 h; optical yield given as percent eeenantioselective reaction;
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
590-13-6
顺式-1-溴-1-丙烯
+
25015-63-8
频哪醇硼烷
→
反应条件
67562-19-0
反应条件
RhCl(PPh3)3 in diethyl ether T=20°C; P=9375940 Torr; 24 h;
参考文献
Colin, Sylvie; Vaysse-Ludot, Lucile; Lecouve, Jean-Pierre; Maddaluno, Jacques
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 24 p. 4505 - 4511
108-86-1
溴代苯
+
124215-44-7
3-溴丙基硼酸频哪醇酯
→
反应条件
92-52-4
联苯
+
67562-19-0
+
1361022-63-0
+
329685-40-7
3-苯基-1-丙基硼酸频哪酯
+
71-43-2
苯
反应条件
pyridine; N,N'-dimethyl-N,N'-propyleneurea; 4,4'-dimethoxy-2,2'-bipyridine; NiI2*3.5H2O; sodium iodide; zinc T=20 - 60°C; 5 h; chemoselective reaction;
参考文献
Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6146 - 6159
347389-75-7
1-丙炔-1-硼酸频哪醇酯
→
反应条件
67562-19-0
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: hydrogen; [Ir((S)-PPh2C6H4C3H3NOiPr)(COD)](tetrakis(3,5-di(trifluoromethyl)phenyl)borate) / dichloromethane / 18 h / 50 °C / 22502.3 Torr View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
1116-61-6
三丙基硼烷
+
67-63-0
异丙醇
→
反应条件
67562-19-0
反应条件
oxygen in hexane Irradiation;
参考文献
Tokuda,M. et al.
Journal of the Chemical Society, Chemical Communications, 1977 , p. 690 - 691
61676-62-8
异丙醇频哪醇硼酸酯
→
反应条件
67562-19-0
+
1360649-35-9
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C 1.2: 2 h / -78 °C / Inert atmosphere 1.3: -78 - 20 °C / Inert atmosphere 2.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 18 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
347389-75-7
1-丙炔-1-硼酸频哪醇酯
→
反应条件
67562-19-0
+
1360649-35-9
反应条件
1.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 18 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Gaziaesmiloviae, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; Kovacevic, Miroslav; Casar, Zdenko
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1014 - 1018
1360649-09-7
+
1333-74-0
氢气
→
反应条件
反应条件
暂无反应条件数据
参考文献
Gazic Smilovic, Ivana; Casas-Arce, Eva; Roseblade, Stephen J.; Nettekoven, Ulrike; Zanotti-Gerosa, Antonio; et al.
Angew. Chem., 2012 , vol. 51, p. 1014 - 1018
Angewandte Chemie, 2012 , vol. 124, p. 1038 - 1042
347389-75-7
1-丙炔-1-硼酸频哪醇酯
→
反应条件
67562-19-0
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: (cyclooctadiene)((3,5-dimethylphenyl)2PCH2C(CH3)2(C3H3NO)(tBu))Ir(tetrakis(3,5-(trifluoromethyl)phenyl)borate); hydrogen / dichloromethane / 18 h / 50 °C / 22502.3 Torr View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
1116-61-6
三丙基硼烷
+
67-64-1
丙酮
→
反应条件
67562-19-0
反应条件
tetra-(n-butyl)ammonium iodide (electrolysis);
参考文献
Takahashi,Y. et al.
Chemistry Letters, 1978 , p. 669 - 672
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