in benzene-d6
Kinetics; soln. of (C5Me5)2SmMe(THF) in C6D6 prepared in NMR-tube, tube cooled in a liquid nitrogen-bath, evacuated and sealed; after 6 days at room temp. complete convertion;; monitored by (1)H-NMR-spectroscopy;;
参考文献
Evans,W.J.; Chamberlain,L.; Ulibarri,T.
Journal of the American Chemical Society, 1988 , vol. 110, p. 6423
in neat (no solvent, gas phase)
accelerated and energy selected ion beam is injected into a collision cell holding the neutral reactant gas (ambient temp., 2 mTorr); products detected by mass spectrometry;
参考文献
Schilling, J. Bruce; Beauchamp, J. L.
Journal of the American Chemical Society, 1988 , vol. 110, # 1 p. 15 - 24
Jacobson; Bakbtiar
Journal of the American Chemical Society, 1993 , vol. 115, # 23 p. 10830 - 10844
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反应条件
tetrahydrofuran in tetrahydrofuran
D2 (1 atm) was introduced into a flask containing THF soln. of U-complex, soln. was stirred for 10 h at 20°C; (1)H NMR analysis of the reaction mixt., CH3D was detected by MS anal. of the gas phase;
参考文献
Foyentin, Muriel; Folcher, Gerard; Ephritikhine, Michel
Journal of Organometallic Chemistry, 1987 , vol. 335, p. 201 - 206
Bak
Journal of Organic Chemistry, 1956 , vol. 21, p. 797
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Schissler et al.
Discussions of the Faraday Society, 1951 , vol. 10, p. 46,47
