二(2,2,2-三氟乙氧基)三苯基膦烷合成路线 （共 14 条）
反应条件
water in toluene; acetonitrile T=31°C; H2(18)O, hydrolysis of a series of phosphoranes derived from Ar3P and ArP(OCH2CF3)2; Mechanism;
参考文献
Lowther, Nicholas; Hall, C. Dennis
Journal of the Chemical Society, Chemical Communications, 1985 , # 19 p. 1303 - 1305
反应条件
in diethyl ether; dichloromethane 1 h; Ambient temperature;
参考文献
Kubota, Toshio; Miyashita, Satoshi; Kitazume, Tomoya; Ishikawa, Nobuo
Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5052 - 5057
参考文献
Kubota, Toshio; Miyashita, Satoshi; Kitazume, Tomoya; Ishikawa, Nobuo
Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5052 - 5057
反应条件
bromine in diethyl ether; dichloromethane
T=0°C; 1 h;
参考文献
Kubota, Toshio; Miyashita, Satoshi; Kitazume, Tomoya; Ishikawa, Nobuo
Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5052 - 5057
反应条件
in pentane
12 h; Ambient temperature;
参考文献
Denney,D.B.; Denney,D.Z.; Hammond,P.J.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1785
反应条件
1: triphenylphosphine With bromine in dichloromethane
T=-78°C; 0.166667 h; Inert atmosphere;
2: 2,2,2-trifluoroethanol With triethylamine in diethyl ether; dichloromethane
T=-78 - 20°C; 1.25 h; Inert atmosphere;
参考文献
Morieux, Pierre; Salome, Christophe; Park, Ki Duk; Stables, James P.; Kohn, Harold
Journal of Medicinal Chemistry, 2010 , vol. 53, # 15 p. 5716 - 5726
参考文献
Itzstein, Mark von; Jenkins, Ian D.
Australian Journal of Chemistry, 1983 , vol. 36, # 3 p. 557 - 563
反应条件
1: Br2 / CH2Cl2 / 1 h / Ambient temperature
2: Et3N / CH2Cl2; diethyl ether / 3.5 h / Ambient temperature
View Scheme
参考文献
Yang, Zhen-Yu
Journal of Organic Chemistry, 1995 , vol. 60, p. 5696 - 5698
参考文献
Lowther, Nicholas; Crook, Polly; Hall, Dennis
Phosphorus and Sulfur and the Related Elements, 1987 , vol. 30, p. 405 - 408
反应条件
in diethyl ether; dichloromethane
1 h; Ambient temperature;
参考文献
Kubota, Toshio; Miyashita, Satoshi; Kitazume, Tomoya; Ishikawa, Nobuo
Journal of Organic Chemistry, 1980 , vol. 45, # 25 p. 5052 - 5057
