1,1,1,3,3,3-六氟丙烷-2,2-二醇合成路线 （共 14 条）
参考文献
Allied Chem.Corp.
Patent: FR1385110 , 1963 ;
反应条件
hydrogen fluoride T=-20 - 60°C; Product distribution / selectivity;
参考文献
Central Glass Company, Limited
Patent: EP2189437 A1, 2010 ;
Location in patent: Page/Page column 6 ;
反应条件
water in di-isopropyl ether
T=20°C; Product distribution / selectivity;
参考文献
Central Glass Company, Limited
Patent: US2012/136177 A1, 2012 ;
Location in patent: Page/Page column 4; 5 ;
反应条件
potassium hydroxide; water; fluorine
T=0 - 5°C; 1.5 - 2.33333 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757572 A1, 2007 ;
Location in patent: Page/Page column 6 ;
反应条件
water in dimethyl-ether; dichloromethane-d2
T=-90°C; Title compound not separated from byproducts;
参考文献
Pawar, Diwakar M.; Cain-Davis, Dalephine; Noe, Eric A.
Journal of Organic Chemistry, 2007 , vol. 72, # 6 p. 2003 - 2007
反应条件
cesium fluoride in N,N-dimethyl-formamide
T=10°C; 1 h; Yield given;
参考文献
Rogovik, V. M.; Delyagina, N. I.; Mysov, E. I.; Cherstkov, V. F.; Sterlin, S. R.; German, L. S.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 9.1. p. 1870 - 1876
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 9 p. 2057 - 2063
反应条件
water; potassium iodide in water; acetonitrile
byproducts: I2, KF, NH4(1+); acidified with 1N CH3COOH;
参考文献
Dow Chemical Co.
Patent: US3350448 , 1967 ;
C.A., 1968 , vol. 68, p. 59147
反应条件
water in dichloromethane
72 h; Ambient temperature;
参考文献
Goerlich, Jens R.; Plack, Volker; Schmutzler, Reinhard
Journal of Fluorine Chemistry, 1996 , vol. 76, # 1 p. 29 - 35
反应条件
potassium permanganate in acetone
0.5 h; Heating; Title compound not separated from byproducts;
参考文献
Postovoi, S. A.; Mysov, E. I.; Zeifman, Yu. V.; Knunyants, I. L.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 7 p. 1409 - 1413
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 7 p. 1586 - 1590
反应条件
in chloroform
T=20°C; 1440 h; Mechanism;
参考文献
Chkanikov, N. D.; Vershinin, V. L.; Galakhov, M. V.; Kolomiets, A. F.; Fokin, A. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1989 , vol. 38, # 1.2 p. 113 - 119
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989 , vol. 38, # 1 p. 126 - 132
