5-甲基-5-己烯-3-醇合成路线 （共 5 条）
反应条件
1: in diethyl ether
T=-78°C; allylboration; 3 h;
2: With sodium hydroxide; dihydrogen peroxide in diethyl ether; water
T=-78 - 20°C; Oxidation; 18 h; Further stages.;
参考文献
Barrett, Anthony G. M.; Braddock, D. Christopher; de Koning, Pieter D.; White, Andrew J. P.; Williams, David J.
Journal of Organic Chemistry, 2000 , vol. 65, # 2 p. 375 - 380
反应条件
methanol; (-) NMCpMo(NO)(Cl)(η3-methallyl) in dichloromethane
Ambient temperatureenantioselective syntheses; other allylmolybdenum complexes; Product distribution;
参考文献
Faller, J. W.; Linebarrier, D. L.
Journal of the American Chemical Society, 1989 , vol. 111, # 5 p. 1937 - 1939
反应条件
Mo-complex contg. 37 percent (R)-3 complex and 63 percent (S)-4 complex is treated with propionaldehyde.;
参考文献
Faller, J. W.; Linebarrier, D. L.
Journal of the American Chemical Society, 1989 , vol. 111, # 5 p. 1937 - 1939
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Jadhav, Prabhakar K.; Bhat, Krishna S.; Perumal, P. Thirumalai; Brown, Herbert C.
Journal of Organic Chemistry, 1986 , vol. 51, # 4 p. 432 - 439
反应条件
triethanolamine
1.) hexane, -40 deg C, 2 h; 20 deg C, 12 h, 2.) 2 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Hoffmann, Reinhard W.; Herold, Thomas
Chemische Berichte, 1981 , vol. 114, # 1 p. 375 - 383
