3,4-二甲基-5-己烯-3-醇合成路线 （共 5 条）
反应条件
in acetonitrile
2 h; Heating;
参考文献
Roman, Jose G.; Soderquist, John A.
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9772 - 9775
反应条件
1: in diethyl ether
T=-78°C; allylboration; 3 h;
2: With sodium hydroxide; dihydrogen peroxide in diethyl ether; water
T=-78 - 20°C; Oxidation; 18 h; Further stages.;
参考文献
Barrett, Anthony G. M.; Braddock, D. Christopher; de Koning, Pieter D.; White, Andrew J. P.; Williams, David J.
Journal of Organic Chemistry, 2000 , vol. 65, # 2 p. 375 - 380
反应条件
sodium hydroxide; dihydrogen peroxide; (-)-β-methallyldiisopinocampheylborane
1.) anhydrous ethyl ether, -78 deg C, 1 h, 25 deg C, 1 h. 2.) -78 deg C, 1 h, 30 deg C, 3 h.; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brown, Herbert C.; Jadhav, Prabhakar K.; Perumal, P. Thirumalai
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5111 - 5114
反应条件
triethanolamine
1.) hexane, -40 deg C, 2 h; 20 deg C, 12 h, 2.) 2 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Hoffmann, Reinhard W.; Herold, Thomas
Chemische Berichte, 1981 , vol. 114, # 1 p. 375 - 383
反应条件
(i) (+)-2-exo,-3-exo-dihydroxy-3-endo-phenyl-bornane, THF, (ii) /BRN= 605330/, n-hexane, (iii) (HOCH2CH2)3N; Multistep reaction;
参考文献
Herold,T.; Hoffmann,R.W.
Angewandte Chemie, 1978 , vol. 90, p. 822 - 823
