1H,1H,2H,2H-全氟-1-癸醇 合成路线 (共 46 条)
反应条件
water; sodium carbonate in dichloromethane 1 h; Ambient temperature;
参考文献
Umemoto, Teruo; Kuriu, Yuriko; Nakayama, Shin-ichi
Tetrahedron Letters, 1982 , vol. 23, # 11 p. 1169 - 1172
2043-53-0 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 +
→
反应条件
17741-60-5 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 7-8 ;
2043-53-0 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 +
→
反应条件
反应条件
silver(l) oxide T=80 - 120°C; 1 - 4 h; Product distribution / selectivity;
参考文献
US2007/123731 A1, ;
Page/Page column 3-4 ;
→
反应条件
647-42-7 3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇 +
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
US6664430 B1, ;
Page column 8-9 ;
2043-53-0 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 +
→
反应条件
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 6-7; 8-9 ;
2043-53-0 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 +
→
反应条件
反应条件
T=100°C; 4 h; Product distribution / selectivity;
参考文献
US2007/123731 A1, ;
Page/Page column 5 ;
反应条件
Candida rugosa lipase in hexane T=40°C; 25 h;
参考文献
Beier, Petr; O'Hagan, David
Chemical Communications, 2002 , # 16 p. 1680 - 1681
反应条件
1.1: 88 percent / Et3N / tetrahydrofuran / 10 h / Heating 2.1: 93 percent / LiBr / acetone / 7 h / Heating 3.1: Mg; I2 / tetrahydrofuran / 4 h / Heating 3.2: tetrahydrofuran / -6 - 24 °C View Scheme
参考文献
Hungerhoff, Benno; Sonnenschein, Helmut; Theil, Fritz
Journal of Organic Chemistry, 2002 , vol. 67, # 6 p. 1781 - 1785
反应条件
chromium(VI) oxide; sulfuric acid in diethyl ether; acetone 0.0833333 h;
参考文献
Achilefu, Samuel; Mansuy, Laurence; Selve, Claude; Thiebaut, Sylvie
Journal of Fluorine Chemistry, 1995 , vol. 70, # 1 p. 19 - 26
反应条件
air; chlorine T=22.85°C; P=750 Torr; UV-irradiation; Product distribution;
参考文献
Ellis, David A.; Martin, Jonathan W.; De Silva, Amila O.; Mabury, Scott A.; Hurley, Michael D.; Sulbaek Andersen, Mads P.; Wallington, Timothy J.
Environmental Science and Technology, 2004 , vol. 38, # 12 p. 3316 - 3321