1H,1H,2H,2H-全氟-1-癸醇合成路线 （共 46 条）
→
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
反应条件
1H-imidazole; iodine; triphenylphosphine in diethyl ether; acetonitrile T=20°C; 19 h;
参考文献
Carrel, Frederic R.; Seeberger, Peter H.
Journal of Organic Chemistry, 2008 , vol. 73, # 6 p. 2058 - 2065
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
→
344580-04-72,2,2-三氟乙基4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷酸酯
反应条件
1.1: 88 percent / Et3N / tetrahydrofuran / 10 h / Heating 2.1: 93 percent / LiBr / acetone / 7 h / Heating 3.1: Mg; I2 / tetrahydrofuran / 4 h / Heating 3.2: tetrahydrofuran / -6 - 24 °C 4.1: 84 percent / PCl5 / diethyl ether / 4 h / Heating 5.1: 91 percent / DMAP; pyridine / tetrahydrofuran / 0 - 20 °C View Scheme
参考文献
Hungerhoff, Benno; Sonnenschein, Helmut; Theil, Fritz
Angewandte Chemie - International Edition, 2001 , vol. 40, # 13 p. 2492 - 2494
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
反应条件
1: Et3N, POCl3 / diethyl ether / 1 h / 0 °C 2: Et3N / diethyl ether / 0 °C View Scheme
参考文献
Krafft; Vierling; Riess
European Journal of Medicinal Chemistry, 1991 , vol. 26, # 5 p. 545 - 550
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane; 1,2,2-trifluoro-trichloroethane T=30°C; 18 h;
参考文献
Krupers, Maarten J.; Moeller, Martin
Journal of Fluorine Chemistry, 1997 , vol. 82, # 2 p. 119 - 124
反应条件
dicyclohexyl-carbodiimide; 4-(N,N-dimethlyamino)pyridine in 1,2,2-trifluoro-trichloroethane 5 h; Ambient temperature;
参考文献
Hoepken, Jens; Faulstich, Sabine; Moeller, Martin
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1992 , vol. 210, p. 59 - 74
反应条件
carbon tetrabromide; triphenylphosphine in dichloromethane T=20°C; 14 h;
参考文献
Emnet, Charlotte; Weber, Kathleen M.; Vidal, Jose A.; Consorti, Crestina S.; Stuart, Alison M.; Gladysz
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 12-13 p. 1625 - 1634
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17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 7-8 ;
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
