1H,1H,2H,2H-全氟-1-癸醇合成路线 （共 46 条）
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 7-8 ;
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
→
113823-56-63,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟癸基4-甲基苯磺酸酯
反应条件
triethylamine in dichloromethane T=0 - 20°C; Tosylation;
参考文献
Elshani, Sadik; Kobzar, Evgeny; Bartsch, Richard A.
Tetrahedron, 2000 , vol. 56, # 21 p. 3291 - 3301
反应条件
1: 72.3 percent / pyridine / CH2Cl2; dioxane / 0.5 h / 0 °C 2: 54.6 percent / NaN3 / acetone; H2O / 2 h / Heating View Scheme
参考文献
Briza, Tomas; Kvicala, Jaroslav; Mysik, Petr; Paleta, Oldzich; Cermak, Jan
Synlett, 2001 , # 5 p. 685 - 687
反应条件
Dess-Martin periodane in dichloromethane
0.333333 h; Ambient temperature;
参考文献
Leveque, Laurence; Le Blanc, Maurice Le; Pastor, Raphael
Tetrahedron Letters, 1998 , vol. 39, # 48 p. 8857 - 8860
反应条件
Dess-Martin periodane in dichloromethane
0.333333 h; Ambient temperature;
参考文献
Leveque, Laurence; Le Blanc, Maurice Le; Pastor, Raphael
Tetrahedron Letters, 1998 , vol. 39, # 48 p. 8857 - 8860
反应条件
Fascat 2003
T=200 - 250°C; 12 h;
参考文献
E. I. du Pont de Nemours and Company
Patent: US6734320 B2, 2004 ;
Location in patent: Page column 12-13 ;
反应条件
pyridinium chlorochromate in dichloromethane
T=20°C; 24 h;
参考文献
Lee, Chan Woo; Hwang, Ho Yun; Park, Joo Yuen; Chi, Ki-Whan
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 5 p. 1305 - 1308
反应条件
Dess-Martin periodane in dichloromethane
0.333333 h; Ambient temperature;
参考文献
Leveque, Laurence; Le Blanc, Maurice Le; Pastor, Raphael
Tetrahedron Letters, 1998 , vol. 39, # 48 p. 8857 - 8860
反应条件
oxalyl dichloride; dimethyl sulfoxide; triethylamine in dichloromethane
T=-50°C; 0.25 h; Yield givenYields of byproduct given;
参考文献
Leveque, Laurence; Le Blanc, Maurice Le; Pastor, Raphael
Tetrahedron Letters, 1998 , vol. 39, # 48 p. 8857 - 8860
