1H,1H,2H,2H-全氟-1-癸醇 合成路线 (共 46 条)
反应条件
trichloroisocyanuric acid; sodium acetate; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical
Title compound not separated from byproducts;
参考文献
Pozzi, Gianluca; Quici, Silvio; Shepperson, Ian
Tetrahedron Letters, 2002 , vol. 43, # 35 p. 6141 - 6143
反应条件
air; chlorine
T=22.85°C; P=750 Torr; UV-irradiation; Product distribution;
参考文献
Ellis, David A.; Martin, Jonathan W.; De Silva, Amila O.; Mabury, Scott A.; Hurley, Michael D.; Sulbaek Andersen, Mads P.; Wallington, Timothy J.
Environmental Science and Technology, 2004 , vol. 38, # 12 p. 3316 - 3321
→
反应条件
89373-67-1 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一酰氯
反应条件
1.1: 88 percent / Et3N / tetrahydrofuran / 10 h / Heating
2.1: 93 percent / LiBr / acetone / 7 h / Heating
3.1: Mg; I2 / tetrahydrofuran / 4 h / Heating
3.2: tetrahydrofuran / -6 - 24 °C
4.1: 84 percent / PCl5 / diethyl ether / 4 h / Heating
View Scheme
参考文献
Hungerhoff, Benno; Sonnenschein, Helmut; Theil, Fritz
Angewandte Chemie - International Edition, 2001 , vol. 40, # 13 p. 2492 - 2494
反应条件
1: With sodium sulfate; Candida rugosa lipase in hexane
T=40°C; 95 h;
2: With Candida rugosa lipase in phosphate buffer
T=20°C; pH=7; 96 h; Further stages.;
参考文献
Beier, Petr; O'Hagan, David
Chemical Communications, 2002 , # 16 p. 1680 - 1681
→
反应条件
64018-23-1 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟癸酰氯
反应条件
1: 95 percent / CrO3, H2SO4 / acetone; diethyl ether / 0.08 h
2: 85 percent / PCl5 / diethyl ether / 2 h / Heating
View Scheme
参考文献
Achilefu, Samuel; Mansuy, Laurence; Selve, Claude; Thiebaut, Sylvie
Journal of Fluorine Chemistry, 1995 , vol. 70, # 1 p. 19 - 26
反应条件
air; chlorine
T=22.85°C; P=750 Torr; UV-irradiation; Product distribution;
参考文献
Ellis, David A.; Martin, Jonathan W.; De Silva, Amila O.; Mabury, Scott A.; Hurley, Michael D.; Sulbaek Andersen, Mads P.; Wallington, Timothy J.
Environmental Science and Technology, 2004 , vol. 38, # 12 p. 3316 - 3321