反式-BETA-苯乙烯硼酸合成路线 （共 109 条）
反应条件
caesium carbonate; tetrakis(triphenylphosphine) palladium(0) in water; N,N-dimethyl-formamide
T=50°C; Suzuki reaction; 2 h; Title compound not separated from byproducts;
参考文献
Oh, Chang Ho; Lim, Young Mook; You, Choong Ho
Tetrahedron Letters, 2002 , vol. 43, # 26 p. 4645 - 4648
反应条件
1,10-phenanthroline; 4 A molecular sieve; oxygen; copper diacetate in dichloromethane; dimethyl sulfoxide
T=40°C; 72 h; atmospheric pressure;
参考文献
Yang, Haijun; Li, Yong; Jiang, Min; Wang, Junmei; Fu, Hua
Chemistry - A European Journal, 2011 , vol. 17, # 20 p. 5652 - 5660
反应条件
copper(I) thiophene-2-carboxylate; triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in diethyl ether
T=20°C; 3 h; Schlenk techniqueInert atmosphere;
参考文献
Ogawa, Daisuke; Hyodo, Keita; Suetsugu, Masato; Li, Jing; Inoue, Yoshiaki; Fujisawa, Mamoru; Iwasaki, Masayuki; Takagi, Kentaro; Nishihara, Yasushi
Tetrahedron, 2013 , vol. 69, # 12 p. 2565 - 2571
反应条件
air; Cu(I)-3-methylsalicylate in N,N-dimethyl-formamide
T=50°C; Miyaura-Suzuki reaction;
参考文献
Villalobos, Janette M.; Srogl, Jiri; Liebeskind, Lanny S.
Journal of the American Chemical Society, 2007 , vol. 129, # 51 p. 15734 - 15735
反应条件
sodium lauryl sulfate; potassium carbonate; palladium dichloride in water
T=60°C; 6 h;
参考文献
Xin, Bingwei; Zhang, Yuhong; Cheng, Kai
Synthesis, 2007 , # 13 p. 1970 - 1978
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; potassium phosphate; palladium diacetate in toluene
T=90°C; 7 h;
参考文献
Fang, Yuan-Qing; Lautens, Mark
Journal of Organic Chemistry, 2008 , vol. 73, # 2 p. 538 - 549
反应条件
Pd(PPh2)(m-C6H4SO3Na)*(H2O)4; sodium carbonate in methanol; water
T=80°C; 3 h;
参考文献
Casalnuovo, Albert L.; Calabrese, Joseph C.
Journal of the American Chemical Society, 1990 , vol. 112, # 11 p. 4324 - 4330
反应条件
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(I) thiophene-2-carboxylate; trifuran-2-yl-phosphane in tetrahydrofuran
T=50°C; 18 h;
参考文献
Liebeskind; Srogl
Journal of the American Chemical Society, 2000 , vol. 122, # 45 p. 11260 - 11261
反应条件
Pd2(dba)3*CHCl3/tris(2-furyl)phosphine in tetrahydrofuran
addn. of 1.6 equiv. of C4H3SCOOCu to the reaction of CF3COSC6H4CH3 (1 equiv.) with (CHCHC6H5)B(OH)2 (1 equiv.) in THF in presence of 1percent Pd2(dba)3*CHCl3/(tris-2-furylphosphine), holding for 18 h at 50°C;
参考文献
Liebeskind; Srogl
Journal of the American Chemical Society, 2000 , vol. 122, # 45 p. 11260 - 11261
反应条件
copper(l) iodide; potassium carbonate in ethylene glycol dimethyl ether; N,N-dimethyl-formamide
T=20°C; 1 h;
参考文献
Yu, Chan-Mo; Kweon, Jae-Hong; Ho, Pil-Su; Kang, Sin-Cheol; Lee, Gong Yeal
Synlett, 2005 , # 17 art. no. U23005ST, p. 2631 - 2634
