反式-BETA-苯乙烯硼酸合成路线 (共 109 条)
反应条件
palladium diacetate; sodium acetate; ethyl acrylate in acetic acid T=25°C; 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 465, # 1-2 p. 85 - 92
反应条件
1: caesium carbonate; tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane / 1,4-dioxane; water / 65 °C / |Inert atmosphere 2: bis-triphenylphosphine-palladium(II) chloride; sodium tetrahydroborate; N,N,N',N,-tetramethylethylenediamine / tetrahydrofuran / 5 h / 25 °C / |Inert atmosphere View Scheme
参考文献
Chelucci, Giorgio
Chemical Communications, 2014 , vol. 50, # 31 p. 4069 - 4072
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=25°C; P=760 Torr; 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 496, # 2 p. 221 - 226
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=25°C; P=760 Torr; 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 496, # 2 p. 221 - 226
反应条件
copper(l) iodide; potassium carbonate in N,N-dimethyl-formamide T=60°C; 2 h;
参考文献
Zhang, Guoying; Zhang, Lingli; Hu, Maolin; Cheng, Jiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 2-3 p. 291 - 294
反应条件
potassium carbonate in N,N-dimethyl-formamide T=60°C; 2 h;
参考文献
Zhang, Guoying; Zhang, Lingli; Hu, Maolin; Cheng, Jiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 2-3 p. 291 - 294
反应条件
2,9-dimethyl-1,10-phenanthroline; palladium (II) trifluoroacetate; oxygen; lithium trifluoroacetate in 1-methyl-pyrrolidin-2-one T=40°C; Heck Reaction; P=760.051 Torr; 2.5 h; Inert atmosphere; Catalytic behavior; Reagent/catalystSolventTime; regioselective reaction;
参考文献
Zheng, Changwu; Wang, Dian; Stahl, Shannon S.
Journal of the American Chemical Society, 2012 , vol. 134, # 40 p. 16496 - 16499,4
反应条件
chloro(ethylene)rhodium(I) dimer in 1,4-dioxane 16 h; Heating;
参考文献
Frost; Wadsworth
Chemical Communications, 2001 , # 22 p. 2316 - 2317
反应条件
1: 90 percent / K2CO3; [Pd(C3H5)Cl]2/Tedicyp / dimethylformamide / 24 h / 130 °C 2: 78 percent / K2CO3; [Pd(C3H5)Cl]2/Tedicyp / dimethylformamide / 20 h / 130 °C View Scheme
参考文献
Cho, Chan Sik; Uemura, Sakae
Journal of Organometallic Chemistry, 1994 , vol. 465, # 1-2 p. 85 - 92
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethylene glycol dimethyl ether; water T=85°C; Suzuki-Miyaura cross-coupling; 1 h; Microwave irradiation;
参考文献
Borrmann, Thomas; Abdelrahman, Aliaa; Volpini, Rosaria; Lambertucci, Catia; Alksnis, Edgars; Gorzalka, Simone; Knospe, Melanie; Schiedel, Anke C.; Cristalli, Gloria; Mueller, Christa E.
Journal of Medicinal Chemistry, 2009 , vol. 52, # 19 p. 5974 - 5989