反式-BETA-苯乙烯硼酸合成路线 （共 109 条）
反应条件
2,9-dimethyl-1,10-phenanthroline; palladium (II) trifluoroacetate; oxygen; lithium trifluoroacetate in 1-methyl-pyrrolidin-2-one T=40°C; Heck Reaction; P=760.051 Torr; 0.5 h; Inert atmosphere; Catalytic behavior; Reagent/catalystSolventTime; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 134, # 40 p. 16496 - 16499,4
反应条件
potassium phosphate; [2,6-bis(3-(2,6-diisopropylphenyl)imidazolin-2-ylidene)pyridine]chloronickel tetrafluoroborate in Sec-butyl alcohol T=100 - 120°C; Suzuki-Miyaura coupling;
参考文献
Journal of Organometallic Chemistry, , vol. 694, # 3 p. 389 - 396
反应条件
1: 90 percent / KHF2 / diethyl ether; H2O / 3 h / 20 °C 2: 80 percent / t-BuNH2 / PdCl2(dppf)*CH2Cl2 / propan-2-ol; H2O / 6 h / Heating View Scheme
参考文献
Reilly, Maureen K.; Rychnovsky, Scott D.
Synlett, 2011 , # 16 art. no. S05411ST, p. 2392 - 2396
反应条件
1,10-phenanthroline; 4 A molecular sieve; oxygen; copper diacetate in dichloromethane; dimethyl sulfoxide T=40°C; 72 h; atmospheric pressure;
参考文献
Huang, Fang; Batey, Robert A.
Tetrahedron, 2007 , vol. 63, # 32 p. 7667 - 7672
反应条件
SIDip*HCl; palladium diacetate in tetrahydrofuran T=20°C; Sizuki-Miyaura cross coupling; 3.5 h;
参考文献
Andrus; Song
Organic letters, 2001 , vol. 3, # 23 p. 3761 - 3764
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran T=20 - 50°C; Suzuki-Miyaura reaction; 16 h; Inert atmosphere;
参考文献
Lin, Hao; Dong, Xicheng; Li, Yuxue; Shen, Qilong; Lu, Long
European Journal of Organic Chemistry, 2012 , # 25 p. 4675 - 4679
反应条件
KHF2 in methanol; water T=20°C; Fluorination;
参考文献
European Journal of Organic Chemistry, , # 8 p. 1875 - 1883
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in tetrahydrofuran; water 3 h; Heating;
参考文献
Urdaneta, Neudo; Ruiz, Jacqueline; Zapata, Antonio J.
Journal of Organometallic Chemistry, 1994 , vol. 464, # 1 p. C33 - C34
反应条件
tris(dibenzylideneacetone)dipalladium (0); sodium carbonate; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride in tetrahydrofuran Suzuki-Miyaura cross-coupling; Heating;
参考文献
Dubbaka, Srinivas Reddy; Vogel, Pierre
Organic Letters, 2004 , vol. 6, # 1 p. 95 - 98
反应条件
tetrabutylammomium bromide; sodium carbonate; palladium diacetate in water T=150°C; Suzuki coupling; 0.0833333 h; microwave irradiation;
参考文献
Arvela, Riina K.; Leadbeater, Nicholas E.; Sangi, Michael S.; Williams, Victoria A.; Granados, Patricia; Singer, Robert D.
Journal of Organic Chemistry, 2005 , vol. 70, # 1 p. 161 - 168
