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1: (i) Na, EtOH, (ii) NaOH, MeOH, (iii) aq. HCl 2: H2 / Pd-C View Scheme

1: (i) Na, EtOH, (ii) NaOH, MeOH, (iii) aq. HCl 2: H2 / Pd-C View Scheme

1.1: Ba / tetrahydrofuran / 0.5 h / -78 °C 1.2: 57 percent / tetrahydrofuran / 0.5 h / -78 °C 2.1: 84 percent / LiAlH4 / tetrahydrofuran / 7 h / 60 °C 3.1: 100 percent / imidazole / dimethylformamide / 20 °C 4.1: (R)-2-(o-fluorobenzyloxy)-2'-methoxy-1,1'-binaphthyl*SnCl4 / toluene / 72 h / -78 °C 4.2: ClSiEt3; imidazole / dimethylformamide / 5 h / 20 °C 4.3: TFA*SnCl4 / various solvent(s); toluene / 24 h / -78 °C View Scheme

tris(dibenzylideneacetone)dipalladium(0) chloroform complex 1.) benzene; 2.) irradiation, acetonitrile; Multistep reaction;

lithium biphenylide; BaI2 in tetrahydrofuran T=-78°C; 1 h; Yield given. Yields of byproduct given;

lithium biphenylide; BaI2 1) THF, -78 deg C, 30 min, 2) THF, a) -78 deg C, 3 h, b) 23 deg C, 16 h; Yield given. Multistep reaction;

1: 1.) Pd2(dba)3CHCl3 / 1.) benzene; 2.) irradiation, acetonitrile 2: H2 / Pd/C / ethyl acetate View Scheme

1: NaI / acetone / 1 h / 0 - 2 °C 2: triethylamine / heptane / 5 h / 25 °C / Irradiation View Scheme

(i) Na, EtOH, (ii) NaOH, MeOH, (iii) aq. HCl; Multistep reaction;