双(2,4,6-三甲基苯基)氯化磷合成路线 （共 9 条）
反应条件
1: With magnesium in tetrahydrofuran Metallation; 2: With phosphorus trichoride in tetrahydrofuran T=-78 - 20°C; Substitution;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 72, # 3 p. 563 - 572
反应条件
phosphorus trichoride in diethyl ether T=0 - 25°C; 15 h;
参考文献
Journal of Organometallic Chemistry, , vol. 310, p. 21 - 26
反应条件
phosphorus trichoride in diethyl ether
参考文献
Chemical Communications, , # 6 p. 583 - 584
反应条件
phosphorus trichoride in tetrahydrofuran T=-78 - 20°C; 12 h; Inert atmosphereSchlenk technique;
参考文献
Inorganic Chemistry, , vol. 52, # 11 p. 6694 - 6704
反应条件
phosphorus trichoride in tetrahydrofuran T=-50°C; further reagent: PBr3; Yield given. Title compound not separated from byproducts;
参考文献
Chemische Berichte, , vol. 116, # 5 p. 1947 - 1954
反应条件
1: magnesium / tetrahydrofuran / 4 h / 20 °C / |Inert atmosphere; |Schlenk technique 2: phosphorus trichoride / tetrahydrofuran / 12 h / -78 - 20 °C / |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Inorganic Chemistry, , vol. 52, # 11 p. 6694 - 6704
反应条件
water in diethyl ether Yield given;
参考文献
Beswick, Michael A.; Cromhout, Natalie L.; Harmer, Christopher N.; Palmer, Julie S.; Raithby, Paul R.; Steiner, Alexander; Verhorevoort, Kerry L.; Wright, Dominic S.
Chemical Communications, 1997 , # 6 p. 583 - 584
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=0 - 20°C; Reduction; 1 h;
参考文献
Sasaki, Shigeru; Tanabe, Yoshihiro; Yoshifuji, Masaaki
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 3 p. 563 - 572
反应条件
1: phenylacetylene With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 20°C; 2 h; Inert atmosphere;
2: (mes)2P-Cl in tetrahydrofuran; hexane
T=-78 - 20°C; Inert atmosphere;
参考文献
Spies, Patrick; Schwendemann, Sina; Lange, Stefanie; Kehr, Gerald; Froehlich, Roland; Erker, Gerhard
Angewandte Chemie - International Edition, 2008 , vol. 47, # 39 p. 7543 - 7546
