1-(1-环己烯-1-基磺酰基)-4-甲基苯合成路线 （共 32 条）
反应条件
1: 91 percent / Na2SO3, NaHCO3 / H2O / 2 h / 70 - 80 °C
2: I2 / ethanol; H2O
3: 68 percent / CuCl2, triethylaminium halide / acetonitrile / 40 °C
4: 76 percent / triethylamine / benzene / 48 h / Ambient temperature
View Scheme
参考文献
Liu, Lilian Kao; Chi, Y.; Jen, Kwan-Yue
Journal of Organic Chemistry, 1980 , vol. 45, # 3 p. 406 - 410
反应条件
1: iodine / methanol / 72 h / Ambient temperature
2: DBU / acetonitrile / 0.25 h / Ambient temperature
View Scheme
参考文献
Inomata, Katsuhiko; Kobayashi, Toshifumi; Sasaoka, Shin-ichi; Kinoshita, Hideki; Kotake, Hiroshi
Chemistry Letters, 1986 , p. 289 - 292
反应条件
1: iodine / methanol / 72 h / Ambient temperature
2: DBU / acetonitrile / 0.25 h / Ambient temperature
View Scheme
参考文献
Inomata, Katsuhiko; Kobayashi, Toshifumi; Sasaoka, Shin-ichi; Kinoshita, Hideki; Kotake, Hiroshi
Chemistry Letters, 1986 , p. 289 - 292
反应条件
1: lithium bromide / water / 5.5 h / 80 - 90 °C
2: sodium hydride / tetrahydrofuran / 15 h / 20 °C
View Scheme
参考文献
Chawla, Ruchi; Singh, Atul K.; Yadav, Lal Dhar S.
Tetrahedron, 2013 , vol. 69, # 6 p. 1720 - 1724
反应条件
sodium hydroxide in water; dimethyl sulfoxide
T=100°C; 0.166667 h; equilibrium between allylic and vinylic sulphone; further reaction conditions; D-labelling experiments in D2O; Product distribution;
参考文献
Knight, Derek J.; Lin, Peter; Russell, Simon T.; Whitham, Gordon H.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 2701 - 2706
反应条件
T=150°C; Pyrolysis; Rate constant;
参考文献
Bordwell; Landis
Journal of the American Chemical Society, 1958 , vol. 80, p. 6379,6382
反应条件
T=166°C; Pyrolysis; Rate constant;
参考文献
Bordwell; Landis
Journal of the American Chemical Society, 1958 , vol. 80, p. 6379,6382
反应条件
(i) CCl4, (ii) Et3N; Multistep reaction;
参考文献
da Silva Correa,C.M.M.; Waters,W.A.
Journal of the Chemical Society [Section] C: Organic, 1968 , p. 1874 - 1879
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Arnold, Dennis P.; Burgess-Dean, Leon; Hubbard, Jason; Rahman, M. Abdur
Australian Journal of Chemistry, 1994 , vol. 47, # 5 p. 969 - 974
反应条件
potassium tert-butylate in tetrahydrofuran
Ambient temperatureother bases, solvent, temperatures; various modes and time of reactants mixing; other vinylsulfones and products; Product distribution;
参考文献
Arnold, Dennis P.; Burgess-Dean, Leon; Hubbard, Jason; Rahman, M. Abdur
Australian Journal of Chemistry, 1994 , vol. 47, # 5 p. 969 - 974
