(4-溴苯氧基)叔丁基二甲基硅烷合成路线 （共 45 条）
反应条件
1: 88 percent / n-BuLi 2: 98 percent View Scheme
参考文献
Shiomi, Toshiaki; Nakahodo, Tsukasa; Fujihara, Hisashi
Chemistry Letters, 2012 , vol. 41, # 12 p. 1700 - 1702
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C 1.2: 1.5 h / -78 - 20 °C 1.3: 20 °C 2.1: hydrogenchloride / ethanol; water / 8 h / |Inert atmosphere; |Reflux View Scheme
参考文献
Shrestha, Tej B.; Troyer, Deryl L.; Bossmann, Stefan H.
Synthesis (Germany), 2014 , vol. 46, # 5 art. no. 673, p. 646 - 652
反应条件
1: 1.) t-BuLi / 1.) THF, -78 deg C, 1 h, 2.) THF, from -78 deg C to RT, 2 h 2: tetrabutylammonium fluoride / 0.5 h / 0 °C View Scheme
参考文献
Engman, Lars; Persson, Joachim; Andersson, Carl M.; Berglund, Mats
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 8 p. 1309 - 1313
反应条件
1.1: n-butyl lithium / tetrahydrofuran / 0.5 h / -78 °C 1.2: triisopropyl borate / tetrahydrofuran / -78 - 20 °C 1.3: 65 percent / HCl / tetrahydrofuran; H2O / 0.08 h / 0 °C 2.1: 82 percent / Na2CO3 / Pd(PPh3)4 / 1,2-dimethoxy-ethane; H2O / 95 °C View Scheme
参考文献
Edsall Jr., Richard J; Harris, Heather A; Manas, Eric S; Mewshaw, Richard E
Bioorganic and medicinal chemistry, 2003 , vol. 11, # 16 p. 3457 - 3474
反应条件
phosphomolybdic acid; silica gel in tetrahydrofuran T=20°C; 18 h;
参考文献
Journal of Organic Chemistry, , vol. 70, # 11 p. 4520 - 4523
反应条件
cesium fluoride in N,N-dimethyl-formamide 12 h; Ambient temperature;
参考文献
Oriyama, Takeshi; Noda, Kojiro; Yatabe, Kaori
Synlett, 1997 , vol. 1997, # 6 p. 701 - 703
反应条件
1: 78 percent / CsF / dimethylformamide / 3 h / Ambient temperature 2: 95 percent / NaOMe / dimethylformamide / 0.5 h / Ambient temperature View Scheme
参考文献
Oriyama, Takeshi; Noda, Kojiro; Yatabe, Kaori
Synlett, 1997 , vol. 1997, # 6 p. 701 - 703
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran Ambient temperature;
参考文献
Saunders, D. G.
Synthesis, 1988 , # 5 p. 377 - 379
反应条件
cesium fluoride in N,N-dimethyl-formamide 12 h; Ambient temperature;
参考文献
Oriyama, Takeshi; Noda, Kojiro; Yatabe, Kaori
Synlett, 1997 , vol. 1997, # 6 p. 701 - 703
反应条件
1: 78 percent / CsF / dimethylformamide / 3 h / Ambient temperature 2: 92 percent / NaOMe / dimethylformamide / 0.5 h / Ambient temperature View Scheme
参考文献
Oriyama, Takeshi; Noda, Kojiro; Yatabe, Kaori
Synlett, 1997 , vol. 1997, # 6 p. 701 - 703
