17Alpha-羟基黄体酮合成路线 （共 90 条）
反应条件
1: acetic acid; HBr 2: palladium/charcoal; methanol; ammonium acetate / Hydrogenation 3: water 4: toluene-4-sulfonic acid 5: aluminium isopropylate; cyclohexanone; xylene 6: aqueous methanol.KOH View Scheme
参考文献
Journal of the American Chemical Society, , vol. 78, p. 820,823
反应条件
1: aqueous methanol; HCl 2: CrO3; pyridine / anschliessend mit wss.NaOH View Scheme
参考文献
Journal of the American Chemical Society, , vol. 79, p. 456,458
反应条件
potassium hydroxide; [bis(acetoxy)iodo]benzene in methanol T=20°C; 8 h;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, p. 1709 - 1712
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 8 p. 1909 - 1912
反应条件
trifluoroacetic acid in dichloromethane T=20°C; 1 h; Overall yield = 100 percent;
参考文献
Journal of Labelled Compounds and Radiopharmaceuticals, , vol. 57, # 1 p. 1 - 11
反应条件
pyridine-2-carboxylic acid; dihydrogen peroxide; iron(III) chloride in pyridine; acetic acid 18 h; Ambient temperature; Further byproducts given;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 56, # 5 p. 984 - 990
反应条件
glucose dehydrogenase; D-glucose; nicotinamide adenine dinucleotide phosphate; anhydrous trisodium citrate; magnesium chloride in aq. phosphate buffer T=37°C; pH=7.4; 0.333333 h; Enzymatic reaction; regioselective reaction;
参考文献
FEBS Journal, , vol. 280, # 13 p. 3094 - 3108
反应条件
1: With ethanol; S. cerevisiae GRF18; YEp5117α 30 h; 2: With chromic acid in isopropyl alcohol; acetone T=20°C; 0.333333 h;
参考文献
Russian Journal of Bioorganic Chemistry, , vol. 29, # 6 p. 581 - 587
反应条件
CYP17A1 Enzymatic reaction;
参考文献
ChemBioChem, , vol. 12, # 17 p. 2537 - 2539
反应条件
Cephalosporium aphidicola in ethanol 72 h;
参考文献
Phytochemistry (Elsevier), , vol. 37, # 3 p. 723 - 726
反应条件
1: 57.5 g / acetic acid / methanol / 2 h / 25 °C View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 58, # 3 p. 978 - 980
