三乙基-(三氟乙烯基)硅烷合成路线 （共 10 条）
反应条件
n-butyllithium in tetrahydrofuran; hexane T=-78°C; 3 h;
参考文献
Tetrahedron, , vol. 44, # 13 p. 4135 - 4146
反应条件
cesium fluoride T=180°C; 240 h; polymerization of various trifluorovinylsilanes with various catalysts;
参考文献
Hiyama, Tamejiro; Nishide, Kiyoharu; Obayashi, Michio
Chemistry Letters, 1984 , p. 1765 - 1768
反应条件
tetramethyl-ammonium fluoride in tetrahydrofuran T=-90 - 20°C; Inert atmosphere;
参考文献
Kirij; Dontsova; Pavlenko; Yagupolskii; Tyrra; Naumann
Journal of Fluorine Chemistry, 2010 , vol. 131, # 2 p. 184 - 189
反应条件
in tetrahydrofuran T=-90 - 20°C; Inert atmosphere;
参考文献
Kirij; Dontsova; Pavlenko; Yagupolskii; Tyrra; Naumann
Journal of Fluorine Chemistry, 2010 , vol. 131, # 2 p. 184 - 189
反应条件
n-butyllithium in tetrahydrofuran; hexane; pentane
参考文献
Sagami Chemical Research Center
Patent: US4481366 A1, 1984 ;
反应条件
n-butyllithium in tetrahydrofuran; hexane
1.) -78 deg C; 2.) up to RT, 4 h;
参考文献
Hiyama, Tamejiro; Nishide, Kiyoharu; Obayashi, Michio
Chemistry Letters, 1984 , p. 1765 - 1768
反应条件
methyllithium in diethyl ether
T=-78°C; 4 h;
参考文献
Fontana; Davis; He; Burton
Tetrahedron, 1996 , vol. 52, # 1 p. 37 - 44
反应条件
in diethyl ether
reaction at -78°C, 3 hours;;
参考文献
Gmelin Handbook: F: PerFHalOrg.4, 1.3.3.7, page 17 - 32
反应条件
triethyl halogeno silane in tetrahydrofuran
参考文献
Seyferth, D.; Wada, T.; Maciel, G. A.
Inorganic Chemistry, 1962 , vol. 1, p. 232 - 235
反应条件
in further solvent(s)
solid XeF2 added in three portions to a cold (-33°C) stirred solution of trans-Et3SiCF=CFBF2 in 1,1,1,3,3-pentafluorobutane; soln. stirred at -28 to -32°C for 1 h; not isolated; detected by (19)F-NMR; additionally some unknown fluoroaliphatic products detected;
参考文献
Frohn, Hermann-Josef; Adonin, Nicolay Yu.; Bardin, Vadim V.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2003 , vol. 629, # 14 p. 2499 - 2508
