1: 1.) cuprous chloride / 1.) ether, -45 deg C, 10 min, 2.) ether, from -35 deg C to RT, 2 h 2: 86 percent / lithium chloride, water / dimethylsulfoxide / 14 h / Heating 3: 88 percent / lithium aluminium hydride 4: 5.5 g / pyridine 5: 54 percent / lithium aluminium chloride / diethyl ether / 20 h / 5 °C View Scheme
参考文献
Beckwith, Athelstan L. J.; Easton, Christopher J.; Lawrence, Tony; Serelis, Algirdas K.
Australian Journal of Chemistry, 1983 , vol. 36, # 3 p. 545 - 556
1: ethanol / 7 h / 80 °C
2: 2M potassium hydroxid / H2O / 0.75 h / 18 °C
3: thionyl chloride / benzene / 0.5 h / 60 °C
4: 101 mg / liquid ammonia / tetrahydrofuran / -78 - 17 °C
5: 81 percent / Lawesson's reagent / toluene / 1.5 h / Heating
6: 20 mg / sodium hydride, methyl iodide, water / tetrahydrofuran / 1 h / 50 °C
View Scheme
参考文献
Arnott, David M.; Harrison, Peter J.; Henderson, Graeme B.; Sheng, Zhi-Chu; Leeper, Finian J.; Battersby, Alan R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 265 - 278
