hydrogenchloride; nickel dichloride in water gradual addn. of solid (15)N-enriched NaNO2 to soln. of RuCl3 in 3.5 M HCl in the presence of NiCl2, heating after gas evolution ceased on water bath for approx. 1.5 h; filtration, washing solids with water; X-ray diffraction, NMR;
参考文献
Eme'yanov; Belyaev; Fedotov
Russian Journal of Inorganic Chemistry, 2000 , vol. 45, # 5 p. 728 - 733
phosphate buffer; myoglobin; dimethyldidodecylammonium bromide in water
Electrolysis; using of pyrolytic graphite electrode modified with myoglobin/dimethyldidodecylammonium bromide; bulk electrolysis of Na(15)NO2 soln. at pH = 6 (phosphate buffer) at -1.2 V; GC/MS analysis;
参考文献
Immoos, Chad E.; Chou, Ju; Bayachou, Mekki; Blair, Emek; Greaves, John; Farmer, Patrick J.
Journal of the American Chemical Society, 2004 , vol. 126, # 15 p. 4934 - 4942
phosphate buffer in water
soln. of Na(15)NO2 in H2O and mixt. of NH2OH*HCl with phosphate buffer (pH 7-9) were degassed on the vac. line by successive freeze-pump-thaw cycles, mixed, the reaction was initiated by rotation of the vessel, after 48 h aq. phase was frozen at 194K; collected at 77K;
参考文献
Bonner, Francis T.; Kada, John; Phelan, Kieran G.
Inorganic Chemistry, 1983 , vol. 22, p. 1389 - 1391
[Cu(II)(tris(2-pyridylmethyl)amine)(OH2)][ClO4]2 in water
Electrolysis; pH = 7, -0.40 V (vs. Ag/AgCl); reaction followed by gas chromy. ((14)N(15)NO : (15)N2O = 1 : 0.63);
参考文献
Komeda, Nobutoshi; Nagao, Hirotaka; Kushi, Yoshinori; Adachi, Gin-ya; Suzuki, Masatatsu; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 2 p. 581 - 589
[Cu(tris(2-pyridylmethyl)amine)(H2O)](2+) in water
Electrolysis; pH = 7, -0.40 V (vs. Ag/AgCl); reaction followed by gas chromy.;
参考文献
Komeda, Nobutoshi; Nagao, Hirotaka; Kushi, Yoshinori; Adachi, Gin-ya; Suzuki, Masatatsu; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 2 p. 581 - 589
in not given
0.025 or 0.225 M H(1+); not isolated, isotopic composition detd. by mass spectroscopy; further products: NO, (14)N(15)N;
参考文献
Hughes, Martin N.; Shrimanker, Kishore; Wimbledon, Peter E.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 1634 - 1637
in water; water-d2
H2O2 was added to a soln. of Na-salt in H2O/D2O containing phosphate buffer and NaHCO3, pH 3.1 -5; not sepd., detected by NMR spectra;
thiourea dioxide; Co(II) phthalocyanine tetrasulfonic acid (4.4'.4''.4''') (4-) in water-d2
Kinetics; reaction between SO2(2-) and Na(15)NO3 in aq. NaOD and D2O at 25°C in the presence of Co-complex at pH 13.6, thiourea dioxide added, 26, 65 h; monitored by NMR;
参考文献
Kudrik, Evgeny V.; Makarov, Sergei V.; Zahl, Achim; Van Eldik, Rudi
Inorganic Chemistry, 2005 , vol. 44, # 18 p. 6470 - 6475
