1: 3-methoxybromobenzene With n-butyllithium in tetrahydrofuran
T=-78°C; 1 h; Sealed tubeInert atmosphere;
2: zinc(II) chloride in tetrahydrofuran
T=-78 - 20°C; Sealed tubeInert atmosphere;
参考文献
Dennis, Joseph M.; Calyore, Catherine M.; Sjoholm, Jessica S.; Lutz, J. Patrick; Gair, Joseph J.; Johnson, Jeffrey B.
Synlett, 2013 , vol. 24, # 19 art. no. ST-2013-S0592-L, p. 2567 - 2570
Li(acac) in diethyl ether
reaction of Zn(iPr)2 with IC6H4(OMe) in presence of Li(acac) in mixt. ofEt2O and N-methylpyrrolidinone; detn. by gas chromy.;
参考文献
Kneisel, Florian F.; Dochnahl, Maximilian; Knochel, Paul
Angewandte Chemie - International Edition, 2004 , vol. 43, # 8 p. 1017 - 1021
