反-1,2-二甲基环己胺合成路线 （共 74 条）
反应条件
oxygen; silica gel; ozone 0.5 h; - 78 deg C to r.t.; var. of solvent, temp., time; Product distribution;
参考文献
Zarth, Martin; Meijere, Armin de
Chemische Berichte, 1985 , vol. 118, # 6 p. 2429 - 2449
反应条件
methyl(trifluoromethyl)dioxirane in dichloromethane
T=-22°C; 0.166667 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mello, Rossella; Fiorentino, Michele; Fusco, Caterina; Curci, Ruggero
Journal of the American Chemical Society, 1989 , vol. 111, # 17 p. 6749 - 6757
反应条件
peracetic acid; tris(.mu.-oxo)di[(1,4,7-trimethyl-1,4,7-triazanonane)manganese(IV)] hexafluorophosphate in acetonitrile
T=30°C; 1 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Lindsay Smith, John R.; Shul'pin, Georgiy B.
Tetrahedron Letters, 1998 , vol. 39, # 27 p. 4909 - 4912
反应条件
peracetic acid; tris(.mu.-oxo)di[(1,4,7-trimethyl-1,4,7-triazanonane)manganese(IV)] hexafluorophosphate in acetonitrile
T=30°C; 1 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Lindsay Smith, John R.; Shul'pin, Georgiy B.
Tetrahedron Letters, 1998 , vol. 39, # 27 p. 4909 - 4912
反应条件
C36H26FeN6O14; dihydrogen peroxide in water; acetonitrile
T=20°C; 20 h; Irradiation;
参考文献
Cheng, Shi; Li, Jing; Yu, Xiaoxiao; Chen, Chuncheng; Ji, Hongwei; Ma, Wanhong; Zhao, Jincai
New Journal of Chemistry, 2013 , vol. 37, # 10 p. 3267 - 3273
反应条件
hydrogen; oxygen; acetic acid
T=39.84°C; 0.166667 h; Large scale reaction;
参考文献
Yamanaka, Ichiro; Suzuki, Yuta; Toida, Masashi
Catalysis Today, 2010 , vol. 157, # 1-4 p. 286 - 290
反应条件
peracetic acid; Mn2O3(N,N',N''-trimethyl-1,4,7-triazacyclononane)2; dihydrogen peroxide in acetonitrile
T=30°C; 1 h; reaction in the presence of m-CPBA as peroxy acid; oxidation of saturated hydrocarbons with "H2O2-manganese(IV)complex-peroxycarboxylic acid" reagent; selectivity; effect of peroxy acid; effect of reaction conditions, additives; Product distribution;
参考文献
Shul'pin; Lindsay-Smith
Russian Chemical Bulletin, 1998 , vol. 47, # 12 p. 2379 - 2386
反应条件
oxygen; silica gel; ozone
0.5 h; - 78 deg C to r.t.; var. of solvent, temp., time; Product distribution;
参考文献
Zarth, Martin; Meijere, Armin de
Chemische Berichte, 1985 , vol. 118, # 6 p. 2429 - 2449
反应条件
(PPh4)2[Mn(N)(CN)4]; dihydrogen peroxide; acetic acid in 2,2,2-trifluoroethanol
T=23°C; 5 h; Inert atmosphere; Reagent/catalyst;
参考文献
Ma, Li; Pan, Yi; Man, Wai-Lun; Kwong, Hoi-Ki; Lam, William W.Y.; Chen, Gui; Lau, Kai-Chung; Lau, Tai-Chu
Journal of the American Chemical Society, 2014 , vol. 136, # 21 p. 7680 - 7687
反应条件
2,6-dichloropyridine-N-oxide; tetra-n-butylammonium nitridoosmate(VIII); iron(III) chloride in dichloromethane; acetic acid
T=23°C; 16 h; Product distribution;
参考文献
Yiu, Shek-Man; Wu, Zhi-Biao; Mak, Chi-Keung; Lau, Tai-Chu
Journal of the American Chemical Society, 2004 , vol. 126, # 45 p. 14921 - 14929
