poly(methylhydrosiloxane) in not given to Bu3SnOMe poly(methylhydrosiloxane) was added and stirred at room temp. for 8 h; distillation under reduced pressure;
in neat (no solvent) byproducts: CO2; heating for 9 h at 170-180°C and with a pressure of 1 Torr;;
参考文献
Sutton, Andrew D.; Davis, Benjamin L.; Bhattacharyya, Koyel X.; Ellis, Bobby D.; Gordon, John C.; Power, Philip P.
Chemical Communications, 2010 , vol. 46, # 1 p. 148 - 149
2,2,6,6-tetramethylpiperidine in further solvent(s) byproducts: H2; N2 or Ar; 1,2-dichlorobenzene soln. of nBuSnOTf (0.39 mmol) and 2,2,6,6-tetramethylpiperidine (0.4 mmol) added to soln. of B compd. (0.42 mmol), mixt. stirred at 20°c for 2 h; NMR;
参考文献
European Journal of Inorganic Chemistry, , # 25 p. 3967 - 3975
