三丁基(2-甲基苯基)锡烷合成路线 （共 36 条）
反应条件
aluminium trichloride in dichloromethane T=-78°C; 4 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Chemische Berichte, , vol. 129, # 1 p. 45 - 51
反应条件
n-butyllithium in tetrahydrofuran; hexane
参考文献
American Home Products Corporation
Patent: US5521173 A1, 1996 ;
US 5521173 A
反应条件
tetrakis(triphenylphosphine) palladium(0) in toluene
byproducts: (o-MeC6H4)2, Bu3SnBr; at 115°C for 15 h in sealed thick wall Pyrex glass ampoules;
参考文献
Azizian, Hormoz; Eaborn, Colin; Pidcock, Alan
Journal of Organometallic Chemistry, 1981 , vol. 215, # 1 p. 49 - 58
反应条件
n-butyllithium in not given
a microflow system used; C6H4Br2 reacted with n-C4H9Li at -78°C, reacted with CH3O3SCF3 at -78°C, reacted with n-C4H9Li at 0°C, reacted with Sn compd. at 0°C;
参考文献
Usutani, Hirotsugu; Tomida, Yutaka; Nagaki, Aiichiro; Okamoto, Hideho; Nokami, Toshiki; Yoshida, Jun-Ichi
Journal of the American Chemical Society, 2007 , vol. 129, # 11 p. 3046 - 3047
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / |Inert atmosphere
1.2: 1 h / 0 °C / |Cooling with ice; |Inert atmosphere
2.1: tetrahydrofuran / 20 °C / |Inert atmosphere
View Scheme
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
in acetonitrile-D3
T=25°C; Inert atmosphere; Equilibrium constant;
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
in acetonitrile-D3
T=25°C; Inert atmosphere; Equilibrium constant;
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
in tetrahydrofuran
T=20°C; Inert atmosphere; Equilibrium constant;
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
in tetrahydrofuran
T=20°C; Inert atmosphere; Equilibrium constant;
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); cesium fluoride in tetrahydrofuran
T=50°C; Stille Cross Coupling; 6 h;
参考文献
Lee, Dong-Hwan; Qian, Yingjie; Park, Ji-Hoon; Lee, Jong-Suk; Shim, Sang-Eun; Jin, Myung-Jong
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 9 p. 1729 - 1735
