1,1,3,3,3-五氟-1-丙烯合成路线 (共 64 条)
反应条件
byproducts: H2; Irradiation (UV/VIS); 12 d: no addn. of (CF3)2PH to CF3CHCF2, main amt. of educts unchanged; additional formn. of 13 percent polyphosphanes and yellow inflammable ppt.; yiled of H2: 12 percent;
参考文献
Journal of the Chemical Society [Section] C: Organic, , p. 1370 - 1375
F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
UV-Licht.Irradiation;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1955 , p. 3005,3008
反应条件
(η5-cyclopentadienyl)2TiF2; (Ph)2SiH2 in diethylene glycol dimethyl ether T=20°C; 1 h; Inert atmosphere;
参考文献
Kuehnel, Moritz F.; Holstein, Philipp; Kliche, Meike; Krueger, Juliane; Matthies, Stefan; Nitsch, Dominik; Schutt, Joseph; Sparenberg, Michael; Lentz, Dieter
Chemistry - A European Journal, 2012 , vol. 18, # 34 p. 10701 - 10714
反应条件
(η5-cyclopentadienyl)2TiF2; (Ph)2SiH2 in diethylene glycol dimethyl ether T=20°C; 1 h;
参考文献
Kuehnel, Moritz F.; Lentz, Dieter
Angewandte Chemie - International Edition, 2010 , vol. 49, # 16 p. 2933 - 2936
反应条件
UV-Licht.Irradiation;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1955 , p. 3005,3008
反应条件
water; cesium fluoride in sulfolane
参考文献
Haszeldine,R.N. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1975 , p. 2015 - 2019
反应条件
disulfur dichloride; hydrogen fluoride; boron trifluoride T=50°C; 12 h; Product distribution; Further Variations:Temperatures;
参考文献
Petrov, Viacheslav A.
Journal of Fluorine Chemistry, 2001 , vol. 112, # 2 p. 325 - 327
参考文献
Henne; Waalkes
Journal of the American Chemical Society, 1946 , vol. 68, p. 496
反应条件
iodine cloride T=120°C;
参考文献
Knunjanz et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958 , p. 425;engl.Ausg.S.407
反应条件
nitronium fluorosulfate in hydrogen fluoride 1.) 20 deg C, 6 h, 2.) 60 deg C, 1 h;
参考文献
Fokin, A. V.; Rapkin, A. I.; Krylov, I. N.; Kutenov, A. P.; Studnev, Yu. N.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, # 10 p. 2165 - 2168
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , # 10 p. 2364 - 2367