1,1,3,3,3-五氟-1-丙烯合成路线 (共 64 条)
反应条件
byproducts: H2; Irradiation (UV/VIS); 12 d: no addn. of (CF3)2PH to CF3CHCF2, main amt. of educts unchanged; additional formn. of 13 percent polyphosphanes and yellow inflammable ppt.; yiled of H2: 12 percent;
参考文献
Fields,R. et al.
Journal of the Chemical Society [Section] C: Organic, 1970 , p. 1370 - 1375
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Gmelin Handbook: F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
AlF2.8Cl0.2
T=25°C; 3.5 h;
参考文献
Krespan, Carl G.; Dixon, David A.
Journal of Fluorine Chemistry, 1996 , vol. 77, # 2 p. 117 - 126
反应条件
potassium carbonate in dichloromethane
1.) -196 deg C to room temperature, 2.) room temperature, 5 d;
参考文献
Banks, Ronald E.; Hitchen, Stephen M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , # 7 p. 1593 - 1600
参考文献
Lu, Hengyao; Friedrich, H. Bruce; Burton, Donald J.
Journal of Fluorine Chemistry, 1995 , vol. 75, # 1 p. 83 - 86
参考文献
McBee; Truchan; Bolt
Journal of the American Chemical Society, 1948 , vol. 70, p. 2024
反应条件
UV-Licht.Irradiation;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1955 , p. 3005,3008
反应条件
iodine cloride
T=120°C;
参考文献
Knunjanz et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1958 , p. 425;engl.Ausg.S.407
反应条件
chlorine
zuletzt im UV-Licht;
参考文献
Haszeldine; Steele
Journal of the Chemical Society, 1957 , p. 2193,2196
反应条件
30 h; Irradiation; Further byproducts given;
参考文献
Service, Colin F.; Tipping, Anthony E.
Journal of Fluorine Chemistry, 1982 , vol. 20, p. 135 - 140
反应条件
cyclohexyl-lithium in diethyl ether
T=-196 - -20°C; Inert atmosphere;
参考文献
Kuehnel, Moritz F.; Lentz, Dieter
Dalton Transactions, 2009 , # 24 p. 4747 - 4755