反式-2,2-二甲基-3-己烯合成路线 (共 23 条)
反应条件
1: diethyl ether
2: pyridine
3: 450 °C
View Scheme
参考文献
Benkeser et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 5374,5376
反应条件
in not given
W(CH-t-Bu)(NC6H3-i-Pr2)(OCMe(CF3)2)2 with 20 equiv. of cis-3-hexane;
参考文献
Schaverien, Colin J.; Dewan, John C.; Schrock, Richard R.
Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2771 - 2773
反应条件
hydrogen; potassium hydride; platinum
Multistep reaction;
参考文献
Sato, Fumie; Suzuki, Yoshito; Sato, Masao
Tetrahedron Letters, 1982 , vol. 23, # 44 p. 4589 - 4592
反应条件
2: 1.) H2 2.) KH / 1.) Pt
View Scheme
参考文献
Sato, Fumie; Suzuki, Yoshito; Sato, Masao
Tetrahedron Letters, 1982 , vol. 23, # 44 p. 4589 - 4592
反应条件
1: toluene / 24 h / 90 °C
2: 30 percent Spectr. / t-BuOK / toluene / 0.33 h / 30 °C
3: 12 percent Chromat. / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Bandmann, Heinz; Bartik, Tamas; Bauckloh, Sylvia; Behler, Ansgar; Brille, Frank; et al.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1990 , vol. 30, # 6 p. 193 - 204
反应条件
1: 30 percent Spectr. / t-BuOK / toluene / 0.33 h / 30 °C
2: 12 percent Chromat. / tetrahydrofuran / 1 h / 0 °C
View Scheme
参考文献
Bandmann, Heinz; Bartik, Tamas; Bauckloh, Sylvia; Behler, Ansgar; Brille, Frank; et al.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1990 , vol. 30, # 6 p. 193 - 204
反应条件
in tetrahydrofuran
T=0°C; 1 h;
参考文献
Bandmann, Heinz; Bartik, Tamas; Bauckloh, Sylvia; Behler, Ansgar; Brille, Frank; et al.
Zeitschrift fuer Chemie (Stuttgart, Germany), 1990 , vol. 30, # 6 p. 193 - 204
反应条件
Yield given. Multistep reaction;
参考文献
Barluenga, Jose; Yus, Miguel; Concellon, Jose M.; Bernad, Pablo
Journal of Organic Chemistry, 1983 , vol. 48, # 4 p. 609 - 611
参考文献
Benkeser et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 5374,5376
参考文献
Benkeser et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 5374,5376