2,3,6,7,10,11-六(戊氧基)三亚苯基合成路线 （共 12 条）
反应条件
1: 1.) 9-BrBBN, 2.) H2N(CH2)2OH / 1.) CH2Cl2, 20 deg C, 24 h 2: 1.) NaH, 5-chloro-1-phenyl-1H-tetrazole, 2.) H2 / 2.) 10percent Pd/C / 1.) DMF, 2.) EtOH, THF, 40 deg C, 10 atm, 20 h View Scheme
参考文献
Rego, James A.; Kumar, Sandeep; Dmochowski, Ivan J.; Ringsdorf, Helmut
Chemical Communications, 1996 , # 9 p. 1031 - 1032
反应条件
bromo-1,3,2-benzodioxaborole in dichloromethane 36 h; Ambient temperature;
参考文献
Wright, Paul T.; Gillies, Iain; Kilburn, Jeremy D.
Synthesis, 1997 , # 9 p. 1007 - 1009
反应条件
bromo-1,3,2-benzodioxaborole in dichloromethane 36 h; Ambient temperaturevarious amounts of reagent; other times and temperatures; Product distribution;
参考文献
Kumar, Sandeep; Manickam
Synthesis, 1998 , # 8 p. 1119 - 1122
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
T=80°C;
参考文献
Chiang, Long Y.; Stokes, James P.; Safinya, Cyrus R.; Bloch, Aaron N.
Molecular Crystals and Liquid Crystals (1969-1991), 1985 , vol. 125, p. 279 - 288
反应条件
potassium carbonate in ethanol
24 h; RefluxInert atmosphere;
参考文献
Cammidge, Andrew N.; Gopee, Hemant; Patel, Hitesh
Tetrahedron Letters, 2009 , vol. 50, # 26 p. 3513 - 3515
反应条件
1: CHCl3 / Heating
2: 54 percent / tetrabutylammonium fluoride (TBAF) / tetrahydrofuran / 80 °C
View Scheme
参考文献
Chiang, Long Y.; Stokes, James P.; Safinya, Cyrus R.; Bloch, Aaron N.
Molecular Crystals and Liquid Crystals (1969-1991), 1985 , vol. 125, p. 279 - 288
反应条件
3,4,5,6-tetrachloro-1,2-benzoquinone; sulfuric acid
参考文献
Nguyen Huu Tinh; Bernaud; Sigaud; Destrade
Molecular crystals and liquid crystals, 1981 , vol. 65, # 3-4 p. 307 - 314
反应条件
3,4,5,6-tetrachloro-1,2-benzoquinone; sulfuric acid
参考文献
Nguyen Huu Tinh; Bernaud; Sigaud; Destrade
Molecular crystals and liquid crystals, 1981 , vol. 65, # 3-4 p. 307 - 314
反应条件
bromo-1,3,2-benzodioxaborole in dichloromethane
T=0°C; 48 h; Yield given. Yields of byproduct given;
参考文献
Kumar, Sandeep; Manickam
Synthesis, 1998 , # 8 p. 1119 - 1122
反应条件
bromo-1,3,2-benzodioxaborole in dichloromethane
36 h; Ambient temperaturevarious amounts of reagent; other times and temperatures; Product distribution;
参考文献
Kumar, Sandeep; Manickam
Synthesis, 1998 , # 8 p. 1119 - 1122
