potassium phosphate; palladium diacetate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in water; tert-butyl alcohol T=110°C; Csp2-Csp3 Suzuki-Miyaura cross-coupling; 18 h; Inert atmosphereSealed tube;

1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate; sodium carbonate in tert-butyl alcohol T=20 - 120°C; Suzuki-Miyaura coupling; 18 h;

potassium acetate in tert-butyl alcohol T=90°C; 6 h; Inert atmosphere;

potassium phosphate; dichloro(cycloocta-1,5-diene)palladium(II); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in water; tert-butyl alcohol T=95°C; Suzuki-Miyaura cross-coupling; 22 h; Inert atmosphere;