4-溴-1,2-双(溴甲基)苯合成路线 （共 4 条）
反应条件
phosphorus tribromide in diethyl ether
T=0°C; 7 h; Reflux;
参考文献
Suzuki, Noriyuki; Kishimoto, Kaito; Yamazaki, Kohei; Kumamoto, Takuya; Ishikawa, Tsutomu; Margetic, Davor
Synlett, 2013 , vol. 24, # 19 p. 2510 - 2514
反应条件
N-bromosuccinmide; 2,2'-azo-bisisobutyronitrile in tetrachloromethane
1 h; Heating / reflux;
参考文献
VANDERBILT UNIVERSITY
Patent: WO2008/24435 A2, 2008 ;
Location in patent: Page/Page column 98 ;
反应条件
azobisisobutyronitrile in tetrachloromethane
参考文献
BURNS, Christopher J.; DAIGLE, Denis; LIU, Bin; McGARRY, Daniel; PEVEAR, Daniel C.; TROUT, Robert E. Lee; JACKSON, Randy W.
Patent: US2014/194386 A1, 2014 ;
Location in patent: Page/Page column ;
反应条件
1: diisobutylaluminium hydride / toluene / 20 h / 20 °C / |Cooling with ice; |Inert atmosphere
2: phosphorus tribromide / chloroform / 4 h / 20 °C / |Inert atmosphere; |Cooling with ice
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参考文献
Kitamura, Chitoshi; Taka, Naohiro; Kawase, Takeshi
Research on Chemical Intermediates, 2013 , vol. 39, # 1 p. 139 - 146
