顺式-1,1,1,4,4,4-六氟-2-丁烯合成路线 (共 33 条)
参考文献
Krespan,C.G. et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3428 - 3432
反应条件
T=-235.2°C; 8 h; Title compound not separated from byproducts;
参考文献
O'Gara, John E.; Dailey, William P.
Journal of the American Chemical Society, 1994 , vol. 116, # 26 p. 12016 - 12021
反应条件
hydrogen; Pd-BaSO4
T=100 - 200°C; 0.0166667 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 4 ;
反应条件
hydrogen; copper/nickel/chromium on calcium fluoride
T=350 - 375°C; 0.00833333 - 0.0125 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
hydrogen; palladium on calcium fluoride poisoned with lead acetate
T=200 - 300°C; 0.000694444 - 0.00833333 h; Product distribution / selectivity;
参考文献
E.I.du pont de Nemours and Company
Patent: US2009/12335 A1, 2009 ;
Location in patent: Page/Page column 8 ;
反应条件
sulfur(IV) fluoride
T=120°C; 6 h; autoclave;
参考文献
Burmakov, A. I.; Motnyak, L. A.; Kunshenko, B. V.; Alekseeva, L. A.; Yagupol'skii, L. M.
Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, # 7 p. 1204 - 1209
Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 7 p. 1401 - 1408
反应条件
sulfur(IV) fluoride; hydrogen fluoride
T=100°C; 8 h; autoclave; Yield given;
参考文献
Motnyak, L. A.; Burmakov, A. I.; Kunshenko, B. V.; Neizvestnaya, T. A.; Alekseeva, L. A.; Yagupol'skii, L. M.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, # 4 p. 634 - 640
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 4 p. 720 - 726
反应条件
hydrogen
T=200°C; 2 h; optical yield given as percent de;
参考文献
Stepanov; Delyagina; Cherstkov
Russian Journal of Organic Chemistry, 2010 , vol. 46, # 9 p. 1290 - 1295
反应条件
hydrogen
T=240°C; 4 h; optical yield given as percent de;
参考文献
Stepanov; Delyagina; Cherstkov
Russian Journal of Organic Chemistry, 2010 , vol. 46, # 9 p. 1290 - 1295
反应条件
in solid matrix
T=-261.2°C; 21.5 h; Irradiation;
参考文献
O'Gara, John E.; Dailey, William P.
Journal of the American Chemical Society, 1994 , vol. 116, # 26 p. 12016 - 12021