2-(2-溴苯基)苯甲酸合成路线 （共 16 条）
反应条件
1: 2,2'-dibromobiphenyl With n-butyllithium in diethyl ether
T=-15°C; 1 h;
2: carbon dioxide in diethyl ether
5 h;
参考文献
Tilly, David; Samanta, Subhendu S.; De, Asish; Castanet, Anne-Sophie; Mortier, Jacques
Organic Letters, 2005 , vol. 7, # 5 p. 827 - 830
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in methanol; water
参考文献
Betson, Mark S.; Bracegirdle, Ann; Clayden, Jonathan; Helliwell, Madeleine; Lund, Andrew; Pickworth, Mark; Snape, Timothy J.; Worrall, Christopher P.
Chemical Communications, 2007 , # 7 p. 754 - 756
反应条件
copper
T=260 - 290°C; Erwaermen einer aethanol. Loesung des Reaktionsprodukts mit wss. Natronlauge;
参考文献
Miller; Bachman
Journal of the American Chemical Society, 1935 , vol. 57, p. 2443,2446
反应条件
1: Cu
2: Py / dimethylformamide
3: aq. H2SO4
View Scheme
参考文献
Cirigottis,K.A. et al.
Australian Journal of Chemistry, 1974 , vol. 27, p. 2209 - 2228
反应条件
1: Py / dimethylformamide
2: aq. H2SO4
View Scheme
参考文献
Cirigottis,K.A. et al.
Australian Journal of Chemistry, 1974 , vol. 27, p. 2209 - 2228
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; sodium carbonate / tetrahydrofuran; water / 20 - 80 °C / |Schlenk technique; |Inert atmosphere
2: sodium hydroxide; water / tetrahydrofuran / 80 °C
View Scheme
参考文献
Wang, Yang; Gulevich, Anton V.; Gevorgyan, Vladimir
Chemistry - A European Journal, 2013 , vol. 19, # 47 p. 15836 - 15840
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; sodium carbonate / tetrahydrofuran; water / 20 - 80 °C / |Schlenk technique; |Inert atmosphere
2: sodium hydroxide; water / tetrahydrofuran / 80 °C
View Scheme
参考文献
Wang, Yang; Gulevich, Anton V.; Gevorgyan, Vladimir
Chemistry - A European Journal, 2013 , vol. 19, # 47 p. 15836 - 15840
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol / |Reflux
2: caesium carbonate; copper(I) thiophene-2-carboxylate; N,N,N',N,-tetramethylethylenediamine / water / 0.33 h / 250 °C / 14480.5 Torr / |Microwave irradiation
View Scheme
参考文献
Nealmongkol, Prattya; Tangdenpaisal, Kassrin; Sitthimonchai, Somkid; Ruchirawat, Somsak; Thasana, Nopporn
Tetrahedron, 2013 , vol. 69, # 44 p. 9277 - 9283
反应条件
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol / |Reflux
2: 2-benzoyl-cyclohexanone; caesium carbonate; copper(I) thiophene-2-carboxylate / water / 0.17 h / 300 °C / 12929 Torr / |Microwave irradiation
View Scheme
参考文献
Nealmongkol, Prattya; Tangdenpaisal, Kassrin; Sitthimonchai, Somkid; Ruchirawat, Somsak; Thasana, Nopporn
Tetrahedron, 2013 , vol. 69, # 44 p. 9277 - 9283
参考文献
Cirigottis,K.A. et al.
Australian Journal of Chemistry, 1974 , vol. 27, p. 2209 - 2228
