1: With n-butyllithium in tetrahydrofuran; hexane T=-80 - 20°C; Metallation; 2: With iron (III) acetylacetonate in tetrahydrofuran; hexane T=20°C; Oxidation; hydrolysis; 2.2 h; Title compound not separated from byproducts;
参考文献
Higuchi, Hiroyuki; Yoshida, Shima; Uraki, Yoshiyuki; Ojima, Juro
Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 9 p. 2229 - 2237
1.1: n-BuLi / tetrahydrofuran; hexane / 0.67 h / -78 °C 1.2: 87 percent / tetrahydrofuran; hexane / 2 h / -78 - 20 °C 2.1: CsF / dimethylformamide / 25 °C View Scheme
参考文献
Turner, David J.; Anemian, Remi; MacKie, Philip R.; Cupertino, Domenico C.; Yeates, Stephen G.; Turner, Michael L.; Spivey, Alan C.
Organic and Biomolecular Chemistry, 2007 , vol. 5, # 11 p. 1752 - 1763
Higuchi, Hiroyuki; Nakayama, Taketoshi; Koyama, Haruki; Ojima, Juro; Wada, Tatsuo; Sasabe, Hiroyuki
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2363 - 2378
