1: n-butyl-magnesium chloride With titanium(IV) isopropylate in dichloromethane
T=-78°C; 0.166667 h; Inert atmosphere;
2: benzaldehyde With (R)-3-(3,5-diphenylphenyl)-2,2'-dihydroxy-1,1'-binaphthyl in diethyl ether; dichloromethane
T=0°C; 3 h; Inert atmosphere;
3: With hydrogenchloride; water in diethyl ether; dichloromethane
T=0°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Muramatsu, Yusuke; Kanehira, Shinichi; Tanigawa, Masato; Miyawaki, Yuta; Harada, Toshiro
Bulletin of the Chemical Society of Japan, 2010 , vol. 83, # 1 p. 19 - 32
