反应条件
1: With Pt(dibenzylideneacetone)3; C61H81O4P; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran T=60°C; 3 h; Inert atmosphereSealed tube; 2: With dihydrogen peroxide; sodium hydroxide in tetrahydrofuran T=0 - 20°C; 4 h; Inert atmosphere; Overall yield = 64 percent; Overall yield = 78 mg; diastereoselective reaction;
参考文献
Coombs, John R.; Haeffner, Fredrik; Kliman, Laura T.; Morken, James P.
Journal of the American Chemical Society, 2013 , vol. 135, # 30 p. 11222 - 11231
