1-氯-2,4-二甲基-5-硝基苯合成路线 （共 10 条）
反应条件
sodium nitrite in hydrogenchloride; water
参考文献
VERNALIS RESEARCH LIMITED
Patent: EP1147110 B1, 2003 ;
EP 1147110 B1
反应条件
1: dimethylformamide / 20 °C
2: 60 percent / MgCl2*6H2O / N,N-dimethyl-acetamide / 7 h / 140 - 150 °C
View Scheme
参考文献
Gurjar; Reddy; Murugaiah
Synthesis, 2000 , # 12 p. 1659 - 1661
反应条件
1: N,N-dimethyl-formamide / 12 h / 100 °C
2: sodium chloride / water; dimethyl sulfoxide / 12 h / 160 °C
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参考文献
Gurjar, Mukund K.; Murugaiah; Reddy, Dandepally Srinivasa; Chorghade, Mukund S.
Organic Process Research and Development, 2003 , vol. 7, # 3 p. 309 - 312
反应条件
1: potassium fluoride / N,N-dimethyl-formamide / 12 h / 125 °C / |Inert atmosphere
2: N,N-dimethyl-formamide / 12 h / 100 °C
3: sodium chloride / water; dimethyl sulfoxide / 12 h / 160 °C
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参考文献
Gurjar, Mukund K.; Murugaiah; Reddy, Dandepally Srinivasa; Chorghade, Mukund S.
Organic Process Research and Development, 2003 , vol. 7, # 3 p. 309 - 312
反应条件
antimony(V) pentachloride; chlorine
参考文献
I. G. Farbenind.
Patent: DE510438 , 1926 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 447
Full Text Show Details
Gen. Aniline Works
Patent: US1762018 , 1927 ;
反应条件
sulfuric acid; chlorine; iron(III) chloride
参考文献
I. G. Farbenind.
Patent: DE510438 , 1926 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 447
Full Text Show Details
Gen. Aniline Works
Patent: US1762018 , 1927 ;
反应条件
Diazotization.man fuehrt die Diazoniumverbindung in das Diazopiperidid ueber und kocht dieses mit konz. Salzsaeure;
参考文献
Ahrens
Justus Liebigs Annalen der Chemie, 1892 , vol. 271, p. 17
反应条件
sulfur dioxide; nitric acid; acetic anhydride
参考文献
Varma; Raman
Journal of the Indian Chemical Society, 1935 , vol. 12, p. 540
反应条件
1: NaHS; aqueous ethanol
2: aqueous hydrochloric acid; aqueous sodium nitrite solution / anschliessend Behandeln mit Kupfer(I)-chlorid und konz. wss. Salzsaeure
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参考文献
Beyerman; Wielaert
Recueil des Travaux Chimiques des Pays-Bas, 1952 , vol. 71, p. 1213,1218
参考文献
Ahrens
Justus Liebigs Annalen der Chemie, 1892 , vol. 271, p. 17
