1.1: magnesium; iodine / tetrahydrofuran / 1 h / 20 °C 1.2: 1 h / 20 °C 2.1: pyridinium chlorochromate / dichloromethane / 20 °C View Scheme
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Journal of the American Chemical Society, 2013 , vol. 135, # 44 p. 16344 - 16347
potassium phosphate; tris(dibenzylideneacetone)dipalladium (0) in tert-butyl alcohol T=110°C; 10 h;
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1: 1-bromo-2-chloro-benzene With magnesium; ethylene dibromide in tetrahydrofuran 1.58333 h; 2: (4-chlorophenyl)(pyrimidin-5-yl)methanone With zinc(II) chloride in tetrahydrofuran T=20°C; 0.5 h;
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Location in patent: Page/Page column 16-17 ;
