双环[2.2.1]庚-5-烯-2-酮合成路线 (共 39 条)
反应条件
in acetonitrile T=90°C; 10 h;
参考文献
Tetrahedron Letters, , vol. 23, # 25 p. 2563 - 2566
反应条件
1: 91 percent / NaOH / methanol / 4 h / Heating 2: 84 percent / CrO3*pyridine / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
Helvetica Chimica Acta, , vol. 63, # 4 p. 816 - 823
反应条件
1: 80 percent / MeONa / methanol / 20 h / Ambient temperature 2: 3.6 g / pyridinium chlorochromate, Celite / CH2Cl2 / 1.5 h / Ambient temperature View Scheme
参考文献
Australian Journal of Chemistry, , vol. 37, # 12 p. 2509 - 2524
反应条件
1: 50 percent / HCl / methanol / Ambient temperature 2: 1,4-diazabicyclo<2.2.2>octane / xylene / Heating View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 21 p. 1227 - 1228
反应条件
1: HgCl2 / acetonitrile; H2O 2: 1,4-diazabicyclo<2.2.2>octane / xylene / Heating View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 21 p. 1227 - 1228
反应条件
hydrogenchloride; sodium hydroxide; oxygen; tin(ll) chloride; lithium diisopropyl amide Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 48, # 22 p. 4087 - 4096
反应条件
1: 1.) KCN; 2.) LiAlH4 / 1.) MeOH; 2.) THF 2: HIO4 View Scheme
参考文献
Synlett, , vol. 1997, # 7 p. 786 - 788
反应条件
potassium hydroxide; hydroquinone 1) toluene, 80 deg C, 24 h; 2) EtOH, reflux, 1 h; Yield given. Multistep reaction;
参考文献
Helvetica Chimica Acta, , vol. 66, # 4 p. 1031 - 1038
反应条件
1: 1.) CH3Li / 1.) -78 deg C; 2: H2O/HCl View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 24 p. 1872 - 1873
反应条件
1: methanol. KOH 2: K2cr2O7; acetic acid; aqueous H2SO4 View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , vol. 543, p. 1,21