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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
6940-30-3
合成路线
（共 10 条）
1145-08-0
→
反应条件
6940-30-3
反应条件
bis(1,5-cyclooctadiene)nickel (0); C{N(2,6-iPr2C6H3)CH}2 in tetrahydrofuran; 1,4-dioxane T=110°C; Kumada Cross-Coupling; 24 h; Inert atmosphere;
参考文献
Tadaoka, Hiroshi; Yamakawa, Tetsu
Tetrahedron Letters, 2012 , vol. 53, # 41 p. 5531 - 5534
591-50-4
碘苯
+
135-88-6
N-苯基-2-萘胺
→
反应条件
6940-30-3
反应条件
potassium tert-butylate; [2,6-iPr2C6H3N=C(H)C(H)=NC6H3-2,6-iPr2]; copper(l) iodide in toluene T=120°C; 20 h;
参考文献
Liu, Yu-Hua; Chen, Chen; Yang, Lian-Ming
Tetrahedron Letters, 2006 , vol. 47, # 52 p. 9275 - 9278
7385-85-5
对甲基苯磺酸-2-萘酯
→
反应条件
6940-30-3
反应条件
bis(1,5-cyclooctadiene)nickel (0); C{N(2,6-iPr2C6H3)CH}2 in tetrahydrofuran; 1,4-dioxane T=150°C; Kumada Cross-Coupling; 43 h; Inert atmosphere;
参考文献
Tadaoka, Hiroshi; Yamakawa, Tetsu
Tetrahedron Letters, 2012 , vol. 53, # 41 p. 5531 - 5534
580-13-2
2-溴代萘
+
17425-91-1
1,1,1-三甲基-N,N-二苯基-硅烷胺
→
反应条件
6940-30-3
反应条件
cesium fluoride; bis(dibenzylideneacetone)-palladium(0); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl T=100°C; 1 h; Inert atmosphere;
参考文献
Shimizu, Kenta; Minami, Yasunori; Goto, Osamu; Ikehira, Hideyuki; Hiyama, Tamejiro
Chemistry Letters, 2014 , vol. 43, # 4 p. 438 - 440
580-13-2
2-溴代萘
+
122-39-4
二苯胺
→
反应条件
6940-30-3
反应条件
1: diphenylamine With ethylmagnesium bromide in diethyl ether T=0 - 40°C; 2 h; Inert atmosphere; 2: 2-bromo-naphthalene With lithium bromide; iron(II) chloride in anhydrous xylene T=140°C; 3 h; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Imayoshi, Ryuji; Yoshimoto, Yuya; Ghorai, Sujit K.; Jin, Masayoshi; Takaya, Hikaru; Norisuye, Kazuhiro; Sohrin, Yoshiki; Nakamura, Masaharu
Journal of the American Chemical Society, 2012 , vol. 134, # 50 p. 20262 - 20265
108-86-1
溴代苯
+
135-88-6
N-苯基-2-萘胺
→
反应条件
6940-30-3
反应条件
[NiCl(1-naph)(PPh3)2]; sodium hydride; triphenylphosphine in toluene; white oil T=120°C; 12 h; Inert atmosphere;
参考文献
Gao, Cai-Yan; Cao, Xingbo; Yang, Lian-Ming
Organic and Biomolecular Chemistry, 2009 , vol. 7, # 19 p. 3922 - 3925
135-88-6
N-苯基-2-萘胺
+
108-90-7
氯苯
→
反应条件
6940-30-3
反应条件
1: N-phenyl-N-β-naphthylamine With Ni(PCy3)2Cl2; isopropylmagnesium chloride; tri-cyclo-hexyl-phosphine in tetrahydrofuran; 1,4-dioxane T=20°C; 0.0833333 h; Inert atmosphere; 2: chlorobenzene in tetrahydrofuran; 1,4-dioxane T=20 - 95°C; 12.16 h; Inert atmosphere;
参考文献
Li, Xin-Le; Wu, Wei; Fan, Xin-Heng; Yang, Lian-Ming
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1232 - 1236
7385-85-5
对甲基苯磺酸-2-萘酯
+
122-39-4
二苯胺
→
反应条件
6940-30-3
反应条件
1: diphenylamine With Ni(PCy3)2Cl2; isopropylmagnesium chloride; tri-cyclo-hexyl-phosphine in tetrahydrofuran; 1,4-dioxane T=20°C; 0.0833333 h; Inert atmosphere; 2: C10H7-2-OTs in tetrahydrofuran; 1,4-dioxane T=20 - 95°C; 12.16 h; Inert atmosphere;
参考文献
Li, Xin-Le; Wu, Wei; Fan, Xin-Heng; Yang, Lian-Ming
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1232 - 1236
135-88-6
N-苯基-2-萘胺
+
637-88-7
1,4-环己二酮
→
反应条件
6940-30-3
反应条件
toluene-4-sulfonic acid in toluene 12 h; Heating;
参考文献
Haga, Kazuo; Iwaya, Katsumasa; Kaneko, Ryohei
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 3 p. 803 - 808
90-11-9
1-溴代萘
+
122-39-4
二苯胺
→
反应条件
61231-45-6
N,N-二苯基-1-萘胺
+
6940-30-3
反应条件
iron(III) oxide; potassium tert-butylate in dimethyl sulfoxide T=130°C; 36 h; regioselective reaction;
参考文献
Alakonda, Laxhmaiah; Periasamy, Mariappan
Synthesis, 2012 , vol. 44, # 7 art. no. SS-2011-Z0977-OP, p. 1063 - 1068
