2,4,6-三甲基苯乙醇合成路线 （共 17 条）
反应条件
potassium hydroxide in tert-butyl alcohol T=50°C; Electrochemical reaction; Title compound not separated from byproducts.;
参考文献
Lyalin; Petrosyan
Russian Chemical Bulletin, 2007 , vol. 56, # 3 p. 499 - 503
反应条件
pyridine; thionyl chloride in diethyl ether
参考文献
Olah,G.A. et al.
Journal of the American Chemical Society, 1967 , vol. 89, p. 5259 - 5265
反应条件
potassium hydroxide in tert-butyl alcohol T=50°C; Electrochemical reaction; Title compound not separated from byproducts.;
参考文献
Lyalin; Petrosyan
Russian Chemical Bulletin, 2007 , vol. 56, # 3 p. 499 - 503
反应条件
(i) SOCl2, benzene, (ii) N2H4*H2O, nPrOH; Multistep reaction;
参考文献
Bream,J.B. et al.
Journal of Medicinal Chemistry, 1970 , vol. 13, # 6 p. 1051 - 1057
反应条件
[2,2']bipyridinyl; formic acid; tris(acetonitrile)(η5-2,4-cyclopentadien-1-yl)ruthenium(1+) hexafluorophosphate(1-); water in tetrahydrofuran
T=80°C; 48 h;
参考文献
Li, Le; Herzon, Seth B.
Nature Chemistry, 2014 , vol. 6, # 1 p. 22 - 27
反应条件
1: With benzo[1,3,2]dioxaborole; rhodium complex 2 in toluene
T=20°C; Addition; Hydroboration; 2 h;
2: With sodium hydroxide; water; dihydrogen peroxide in toluene
T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Doucet, Henri; Fernandez, Elena; Layzell, Timothy P.; Brown, John M.
Chemistry - A European Journal, 1999 , vol. 5, # 4 p. 1320 - 1330
反应条件
carbon monoxide; hydrogen; benzene
T=190°C; Reagens 4: Octacarbonyldikobalt; Reagens 5: CoCO3;
参考文献
Wender et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4079,4082
反应条件
diethyl ether; benzene
参考文献
Hauser; Van Eenam
Journal of the American Chemical Society, 1957 , vol. 79, p. 5512,5518
反应条件
1: 2-Bromo-1,3,5-trimethyl-benzene With magnesium
2: oxirane
参考文献
Wessig, Pablo; Teubner, Janek
Synlett, 2006 , # 10 p. 1543 - 1546
反应条件
1: LiAlH4; diethyl ether
2: hydrogen; CO; benzene / 190 °C / Reagens 4: Octacarbonyldikobalt; Reagens 5: CoCO3
View Scheme
参考文献
Wender et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 4079,4082
