二苯基(三甲基硅烷基)-氢化锑合成路线 （共 8 条）
反应条件
in benzene To stibane compound in benzene is added S8, cooling of mixture with cold water and stirring for 0.5 h under Ar.; removal of solvent under vac., distn., elem. anal.;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 44, p. 129 - 134
反应条件
methanol in benzene To methanol is added stibane compound in benzene under Ar and the soln. is stirred at 25°C for 2 h.; removal of volatiles under vac.;
参考文献
Ates, M.; Breunig, H. J.; Guelec, S.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 129 - 134
参考文献
Breunig, H. J.; Knobloch, T. P.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 446, p. 119 - 125
Full Text Show Details
Gmelin Handbook: Sb: Org.Comp.2, 1.2.1.1.15, page 55 - 56
反应条件
lithium in tetrahydrofuran
a 20-fold excess of Li reacts with Sb(C6H5)3 in THF at room temp. for 20 h under Ar, decanting,treating with t-C4H9Cl, at -20°C, evapn. in vac.; washing with pentane, evapn.;
参考文献
Breunig, H. J.; Knobloch, T. P.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 446, p. 119 - 125
Show Details
Gmelin Handbook: Sb: Org.Comp.2, 1.2.1.1.15, page 55 - 56
反应条件
in tetrahydrofuran
byproducts: MgCl2; A soln. of Ph2SbCl in THF is added to Mg and Me3SiCl in THF, the mixture is stirred under Ar for 2 h.; evapn. of solvent under vac., residue is washed (ether), removal of solvent, an oil is obtained;
参考文献
Ates, M.; Breunig, H. J.; Guelec, S.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 129 - 134
反应条件
magnesium in tetrahydrofuran
byproducts: MgBrCl; (Ar), Sb-compd. in THF added to Mg-chips, Me3SiCl added dropwise, stirred for 1 h; THF removed at 0.1 mmHg, washed several times with pentane, removed, distilled at 155°C/0.01 mmHg;
参考文献
Breunig, Hans Joachim; Severengiz, Tevfik
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1982 , vol. 37, # 4 p. 395 - 400
参考文献
Breunig, H. J.; Knobloch, T. P.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 446, p. 119 - 125
Show Details
Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.6.4.2, page 51 - 52
参考文献
Breunig, H. J.; Knobloch, T. P.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1978 , vol. 446, p. 119 - 125
Full Text Show Details
Gmelin Handbook: Sb: Org.Comp.2, 1.2.1.1.15, page 55 - 56
