1.1: potassium carbonate; copper / nitrobenzene / 10 h / 200 - 210 °C
1.2: 84 percent / HCl / ethanol / 20 h / Heating
2.1: 72 percent / palladium acetate / acetic acid / 1.5 h / Heating
3.1: 35 percent / HBr; phosphinic acid / 72 h / 75 - 80 °C
View Scheme
参考文献
Yamamura, Tatsuo; Suzuki, Kyouichi; Yamaguchi, Tatsuya; Nishiyama, Tomihiro
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 2 p. 413 - 419
1: para-iodoanisole With tert.-butyl lithium in tetrahydrofuran
T=-78°C; 1 h;
2: With zinc dibromide in tetrahydrofuran
T=20°C; 0.5 h;
3: 1-bromo-2-iodo-benzene With triphenylphosphine; [Pd(dibenzylideneacetone)2] in tetrahydrofuran
T=20°C;
参考文献
Varela, Jesus A.; Pena, Diego; Goldfuss, Bernd; Denisenko, Dmitri; Kulhanek, Jiri; Polborn, Kurt; Knochel, Paul
Chemistry - A European Journal, 2004 , vol. 10, # 17 p. 4252 - 4264
