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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-碘苯甲醚
合成路线
(共 1687 条)
696-62-8
4-碘苯甲醚
+
1527518-38-2
→
反应条件
61251-58-9
+
43121-41-1
+
43121-37-5
1-([1,1'-联苯]-4-基氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)丁烷-2-酮
+
108-95-2
苯酚
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triphenylphosphine; cesium fluoride in toluene T=100°C; Stille Cross Coupling; 48 h; Schlenk techniqueInert atmosphere; Reagent/catalyst;
参考文献
Herrera Cano, Natividad; Santiago, Ana N.
Tetrahedron, 2014 , vol. 70, # 2 p. 280 - 285
696-62-8
4-碘苯甲醚
+
2042-37-7
2-溴苯腈
→
反应条件
4341-02-0
2-(2-氰基苯基)苯甲腈
+
2132-80-1
4,4-二甲氧基联苯
+
125610-78-8
4-甲氧基-2-氰基联苯
+
100-47-0
苯甲腈
反应条件
pyridine; tetra-n-butylammonium tetrafluoroborate in acetonitrile T=20°C; Electrolysisiron rod as anode; stainless steel grid as cathode;
参考文献
Gomes, Paulo; Fillon, Hyacinthe; Gosmini, Corinne; Labbe, Eric; Perichon, Jacques
Tetrahedron, 2002 , vol. 58, # 42 p. 8417 - 8424
621685-64-1
溴(6-甲基-2-吡啶基)镁
+
696-62-8
4-碘苯甲醚
→
反应条件
4385-63-1
2-(4-甲氧苯基)-6-甲基吡啶
反应条件
C42H64O4P2Pd in tetrahydrofuran T=60°C; Kumada-Corriu coupling reaction; 20 h; Inert atmosphere; chemoselective reaction;
参考文献
Ackermann, Lutz; Potukuchi, Harish K.; Kapdi, Anant R.; Schulzke, Carola
Chemistry - A European Journal, 2010 , vol. 16, # 11 p. 3300 - 3303
696-62-8
4-碘苯甲醚
+
351019-18-6
2-氟-5-吡啶硼酸
→
反应条件
444120-93-8
反应条件
potassium carbonate in ethanol; water T=90°C; Suzuki Coupling; 0.25 h; Microwave irradiation;
参考文献
Bratt, Emma; Verho, Oscar; Johansson, Magnus J; Baeckvall, Jan-Erling
Journal of Organic Chemistry, 2014 , vol. 79, # 9 p. 3946 - 3954
696-62-8
4-碘苯甲醚
+
444120-95-0
→
反应条件
444120-93-8
反应条件
potassium phosphate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide T=65°C;
参考文献
Bouillon, Alexandre; Lancelot, Jean-Charles; Collot, Valerie; Bovy, Philippe R; Rault, Sylvain
Tetrahedron, 2002 , vol. 58, # 14 p. 2885 - 2890
696-62-8
4-碘苯甲醚
→
反应条件
4456-34-2
反应条件
tellurium; potassium hydroxide in dimethyl sulfoxide T=110°C; 10 h; Inert atmosphereSealed tube;
参考文献
Zhang, Shaozhong; Karra, Kranthi; Koe, Adam; Jin, Jin
Tetrahedron Letters, 2013 , vol. 54, # 20 p. 2452 - 2454
696-62-8
4-碘苯甲醚
→
反应条件
104-01-8
+
541-50-4
+
4541-73-5
反应条件
toluene-4-sulfonic acid; iron(II) sulfate 1.) NH3 (liquid), 45 min, 2.) H2O, reflux, 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Leeuwen, Milko van; McKillop, Alexander
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , p. 2433 - 2440
874-14-6
+
696-62-8
4-碘苯甲醚
→
反应条件
42542-99-4
反应条件
copper(l) iodide; caesium carbonate in N,N-dimethyl-formamide T=160°C; 50 h; Inert atmosphere; regioselective reaction;
参考文献
Cernova, Miroslava; Pohl, Radek; Hocek, Michal
European Journal of Organic Chemistry, 2009 , # 22 p. 3698 - 3701
292638-84-7
+
696-62-8
4-碘苯甲醚
→
反应条件
4333-75-9
+
1694-19-5
反应条件
sodium acetate; Pd-montmorillonite in 1-methyl-pyrrolidin-2-one T=150°C; Heck reaction; 2 h;
参考文献
Molnar, Arpad; Papp, Attila
Synlett, 2006 , # 18 p. 3130 - 3134
696-62-8
4-碘苯甲醚
+
4363-35-3
→
反应条件
4333-75-9
+
1694-19-5
反应条件
Pd(OH)2/Fe3O4; sodium carbonate in toluene T=130°C; Suzuki-Miyaura reaction; 24 h;
参考文献
Cano, Rafael; Ramon, Diego J.; Yus, Miguel
Tetrahedron, 2011 , vol. 67, # 30 p. 5432 - 5436
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