顺式-2-丁烯-1-硼酸频那醇酯合成路线 （共 20 条）
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 0.33 h / 90 °C / Inert atmosphere 3: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane T=90°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane T=90°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 3: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: diethyl ether; pentane / 12 h / 20 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 0.33 h / 90 °C / Inert atmosphere 3: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: magnesium sulfate / dichloromethane / 20 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 48 p. 11465 - 11469
反应条件
1: bis(cyclohexanyl)borane / neat (no solvent) / 6 h / -78 - 0 °C / |Glovebox; |Inert atmosphere 2: tri-cyclo-hexyl-phosphine; [Ir(cod)2]BF4; C44H45O4P; hydrogen / 1,2-dichloro-ethane / 5.33 h / 28 °C / |Molecular sieve View Scheme
参考文献
Journal of the American Chemical Society, , vol. 135, # 31 p. 11497 - 11500
反应条件
in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Roux, Florence; Maugras, Isabelle; Poncet, Joel; Niel, Gilles; Jouin, Patrick
Tetrahedron, 1994 , vol. 50, # 18 p. 5345 - 5360
