反式-巴豆基硼酸频哪醇酯合成路线 （共 22 条）
反应条件
in diethyl ether
at -78 to 23°C under Ar; 96-98 percent isomeric purity;
参考文献
Roush,W.R.; Adam,M.A.; Walts,A.E.
Journal of the American Chemical Society, 1986 , vol. 108, p. 3422
反应条件
1: trans-2-butene With n-butyllithium; potassium tert-butylate in tetrahydrofuran; hexane
T=-50°C; 0.5 h;
2: With tri-isopropoxy-borane in tetrahydrofuran; hexane
T=-78°C;
3: 2,3-dimethylbutane-2,3-diol With hydrogenchloride; sodium chloride in tetrahydrofuran
参考文献
Ramachandran, P. Veeraraghavan; Pratihar, Debarshi; Biswas, Debanjan
Chemical Communications, 2005 , # 15 p. 1988 - 1989
反应条件
palladium dichloride in tetrahydrofuran
T=60°C; 12 h; optical yield given as percent destereoselective reaction;
参考文献
Zhang, Ping; Roundtree, Ian A.; Morken, James P.
Organic Letters, 2012 , vol. 14, # 6 p. 1416 - 1419
反应条件
palladium dichloride in tetrahydrofuran
T=60°C; 12 h; optical yield given as percent destereoselective reaction;
参考文献
Zhang, Ping; Roundtree, Ian A.; Morken, James P.
Organic Letters, 2012 , vol. 14, # 6 p. 1416 - 1419
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane
T=90°C; 0.333333 h; Inert atmosphere; optical yield given as percent de;
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
1: magnesium sulfate / dichloromethane / 20 °C / Inert atmosphere
2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere
3: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 0.33 h / 90 °C / Inert atmosphere
View Scheme
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
[Ir(cod)2]BF4; C44H45O4P; hydrogen; tri-cyclo-hexyl-phosphine in 1,2-dichloro-ethane
T=28°C; 5.33 h; Molecular sieve;
参考文献
Miura, Tomoya; Nishida, Yui; Morimoto, Masao; Murakami, Masahiro
Journal of the American Chemical Society, 2013 , vol. 135, # 31 p. 11497 - 11500
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane
T=90°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane
T=90°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere
2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 0.33 h / 90 °C / Inert atmosphere
View Scheme
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
