1-(3,6-二羟基-2,4-二甲氧基苯基)-乙酮合成路线 （共 35 条）
反应条件
sodium 3,4-dimethoxybenzoate T=180°C; unter vermindertem Druck; Erwaermen des Reaktionsprodukts mit aethanol. Kalilauge und Behandeln des danach isolierten Reaktionsprodukts mit Dimethylsulfat, Kaliumcarbonat und Aceton;
参考文献
Murti; Seshadri
Proceedings - Indian Academy of Sciences, Section A, 1948 , # 27 p. 217,220
反应条件
dipotassium peroxodisulfate; sodium hydroxide in water
T=20°C; Elbs Oxidation; 168 h;
参考文献
Twincore Zentrum für Experimentelle und Klinische Infektionsforschung GmbH; CNRS Centre National de la Recherche Scientifique; Université de Strasbourg; Pietschmann, Thomas; Haid, Sibylle; Gentzsch, Juliane; Grethe, Christina; Davioud-Charvet, Elisabeth; Lanfranchi, Don Antoine; Elhabiri, Mourad; Benlloch-Martin, Xavier
Patent: EP2641904 A1, 2013 ;
Location in patent: Paragraph 0091-0092 ;
反应条件
boron trifluoride diethyl etherate in toluene
T=110°C; 18 h; Temperature;
参考文献
TWINCORE GMBH; CNRS; UNIVERSITÉ DE STRASBOURG; PIETSCHMANN, Thomas; HAID, Sibylle; GENTZSCH, Juliane; GRETHE, Christina; DAVIOUD-CHARVET, Elisabeth; LANFRANCHI, Don Antoine; ELHABIRI, Mourad; BENLLOCH-MARTIN, Xavier
Patent: WO2013/139487 A1, 2013 ;
Location in patent: Page/Page column 35 ;
反应条件
3,3-dimethyldioxirane in dichloromethane; acetone
T=0 - 20°C; 0.166667 h;
参考文献
Chu, Han-Wei; Wu, Huan-Ting; Lee, Yean-Jang
Tetrahedron, 2004 , vol. 60, # 11 p. 2647 - 2655
反应条件
1: sodium acetate; zinc-powder
2: nitrobenzene; AlCl3
View Scheme
参考文献
Oliverio; Bargellini
Gazzetta Chimica Italiana, 1948 , vol. 78, p. 386,394
参考文献
Horton,W.J.; Stout,M.G.
Journal of Organic Chemistry, 1962 , vol. 27, p. 830 - 833
反应条件
1: NaOH-solution
2: aluminium chloride; nitrobenzene
View Scheme
参考文献
Chapman; Perkin; Robinson
Journal of the Chemical Society, 1927 , p. 3020
参考文献
Nierenstein
Journal of the Chemical Society, 1917 , vol. 111, p. 9
Show Details
Bargellini
Gazzetta Chimica Italiana, 1919 , vol. 49 II, p. 57
反应条件
carbon disulfide; aluminium trichloride
参考文献
Chapman; Perkin; Robinson
Journal of the Chemical Society, 1927 , p. 3020
Show Details
Bargellini; Bini
Gazzetta Chimica Italiana, 1911 , vol. 41 II, p. 14
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1910 , vol. <5> 19 II, p. 597
反应条件
1: acetone; benzene; K2CO3
2: aq. NaOH solution; aqueous .K2S2O8 / anschlissendes Erwaermen mit Na2SO3 und wss.HCl
View Scheme
参考文献
Sastri; Seshadri
Proceedings - Indian Academy of Sciences, Section A, 1946 , vol. 23, p. 262,266
