N,N-二甲基-氨基甲酸苯基酯合成路线 （共 17 条）
反应条件
1: N-chloro-succinimide; palladium diacetate; trifluorormethanesulfonic acid / 1,2-dichloro-ethane / 11 h / 20 °C / |Sealed tube 2: N-chloro-succinimide; palladium diacetate; trifluorormethanesulfonic acid / 1,2-dichloro-ethane / 10 h / 20 °C / |Sealed tube View Scheme
参考文献
Sun, Xiuyun; Sun, Yonghui; Zhang, Chao; Rao, Yu
Chemical Communications, 2014 , vol. 50, # 10 p. 1262 - 1264
反应条件
Ni(PCy3)2Cl2; sodium t-butanolate; tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether; toluene T=110°C; 24 h; Inert atmosphere;
参考文献
Huang, Kun; Yu, Da-Gang; Zheng, Shu-Fang; Wu, Zhen-Hua; Shi, Zhang-Jie
Chemistry - A European Journal, 2011 , vol. 17, # 3 p. 786 - 791
反应条件
1: N-chloro-succinimide; palladium diacetate; trifluorormethanesulfonic acid / 1,2-dichloro-ethane / 11 h / 20 °C / |Sealed tube 2: palladium diacetate; trifluorormethanesulfonic acid; N-bromosuccinmide / 1,2-dichloro-ethane / 6 h / 20 °C / |Sealed tube 3: hydrazine hydrate / 12 h / 20 °C / |Sealed tube View Scheme
参考文献
Sun, Xiuyun; Sun, Yonghui; Zhang, Chao; Rao, Yu
Chemical Communications, 2014 , vol. 50, # 10 p. 1262 - 1264
反应条件
1: N-chloro-succinimide; palladium diacetate; trifluorormethanesulfonic acid / 1,2-dichloro-ethane / 11 h / 20 °C / |Sealed tube 2: N-chloro-succinimide; palladium diacetate; trifluorormethanesulfonic acid / 1,2-dichloro-ethane / 10 h / 20 °C / |Sealed tube 3: hydrazine hydrate / 2 h / 60 °C / |Sealed tube View Scheme
参考文献
Sun, Xiuyun; Sun, Yonghui; Zhang, Chao; Rao, Yu
Chemical Communications, 2014 , vol. 50, # 10 p. 1262 - 1264
反应条件
n-butyllithium; diisopropylamine in tetrahydrofuran; hexane T=-78 - 20°C; anionic ortho-Fries rearrangement; Inert atmosphere;
参考文献
Assimomytis, Nikos; Sariyannis, Yiannis; Stavropoulos, Georgios; Tsoungas, Petros G.; Varvounis, George; Cordopatis, Paul
Synlett, 2009 , # 17 p. 2777 - 2782
反应条件
1: in tetrahydrofuran T=-78 - 20°C; 2: With iodine in tetrahydrofuran T=-78 - 20°C; Further stages.;
参考文献
Garcia, Felipe; McPartlin, Mary; Morey, James V.; Nobuto, Daisuke; Kondo, Yoshinori; Naka, Hiroshi; Uchiyama, Masanobu; Wheatley, Andrew E. H.
European Journal of Organic Chemistry, 2008 , # 4 p. 644 - 647
反应条件
potassium carbonate in acetonitrile
5 h; Inert atmosphereReflux;
参考文献
John, Alex; Nicholas, Kenneth M.
Journal of Organic Chemistry, 2012 , vol. 77, # 13 p. 5600 - 5605
反应条件
in acetonitrile
T=60°C; 0.5 h;
参考文献
Moertl, M.; Knausz, D.; Kolos, Zs.; Szakacs, L.; Csakvari, B.
Journal of Organometallic Chemistry, 1994 , vol. 482, # 1-2 p. 183 - 186
反应条件
trichlorophosphate
T=100°C; 22 h;
参考文献
Kulkarni; Naik; Tandel; Rajappa
Tetrahedron, 1991 , vol. 47, # 7 p. 1249 - 1256
反应条件
molybdenum(IV) disulfide; oxygen
0.05 h; Irradiation;
参考文献
Villemin, Didier; Hachemi, Messaoud; Lalaoui, Mekki
Synthetic Communications, 1996 , vol. 26, # 13 p. 2461 - 2471
