环戊并[cd]芘-3(4H)-酮合成路线 (共 16 条)
反应条件
sodium tetrahydroborate; toluene-4-sulfonic acid 1.) EtOH, 2.) toluene, reflux; Yield given. Multistep reaction;
参考文献
Tintel, C.; Cornelisse, J.; Lugtenburg, J.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 1 p. 14 - 20
反应条件
iodine; silver nitrate; sodium nitrite in acetonitrile
T=0°C; 2.16667 h;
参考文献
Braken-van Leersum, A. M. van den; Spijker, N. M.; Lugtenburg, J.; Cornelisse, J.
Recueil des Travaux Chimiques des Pays-Bas, 1987 , vol. 106, # 12 p. 628 - 640
参考文献
Tintel, C.; Cornelisse, J.; Lugtenburg, J.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 1 p. 14 - 20
反应条件
lithium carbonate in tetrachloromethane
Cyclization; Irradiation;
参考文献
Murray, Robert W.; Singh, Megh
Chemical Research in Toxicology, 1995 , vol. 8, # 2 p. 239 - 243
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in toluene
20 h; Heating;
参考文献
Tintel, C.; Cornelisse, J.; Lugtenburg, J.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 1 p. 14 - 20
反应条件
in tetrachloromethane
3 h; Irradiation;
参考文献
Minabe, Masahiro; Nishimura, Ryuuji; Kimura, Takao; Tsubota, Motohiro
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 4 p. 1248 - 1253
反应条件
1: 71 percent / AlCl3 / CH2Cl2 / 0 °C
2: 43 percent / CCl4 / 3 h / Irradiation
View Scheme
参考文献
Minabe, Masahiro; Nishimura, Ryuuji; Kimura, Takao; Tsubota, Motohiro
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 4 p. 1248 - 1253
反应条件
1: 72 percent / DDQ / benzene / 3 h / Heating
2: 70 percent / polyphosphoric acid / 2 h / 70 - 125 °C
View Scheme
参考文献
Tintel, C.; Cornelisse, J.; Lugtenburg, J.
Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 1 p. 14 - 20
反应条件
1: 57 percent / Br2
2: 43 percent / CCl4 / 3 h / Irradiation
View Scheme
参考文献
Minabe, Masahiro; Nishimura, Ryuuji; Kimura, Takao; Tsubota, Motohiro
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 4 p. 1248 - 1253
反应条件
1: (i) NBS, (PhCO)2O2, (ii) /BRN= 4652394/
2: aq. KOH
3: HF
View Scheme
参考文献
Konieczny,M.; Harvey,R.G.
Journal of Organic Chemistry, 1979 , vol. 44, # 13 p. 2158 - 2160