1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=20°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
NADPH in dimethyl sulfoxide T=30°C; pH=7.4; Product distribution; Further Variations:Reagents;
参考文献
Chemical Communications, , # 8 p. 966 - 968
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反应条件
in tetrahydrofuran A soln. of PhCH2COMe in THF was added to a suspn. of complex in THF at -78°C; 1 h;; evapd., chromy. on silica; eluent - ethyl acetate-light petroleum;;
参考文献
Atwood, Jerry L.; Bott, Simon G.; Hitchcock, Peter B.; Eaborn, Colin; Shariffudin, Rio S.; et al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 747 - 756
1: With CF3O3S(1-)*C45H36F3N2PRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=0°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C;
